3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose

Base Information

Chemical Name:3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose
CAS No.:1448242-49-6
Molecular Formula:C₄₆H₅₆O₁₁Si
Molecular Weight:813.03
Hs Code.:

Synonyms:3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose

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Chemical Property of 3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose

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Technology Process of 3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose

There total 4 articles about 3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 127072-92-8
3,3'-di-o-benzyl-4,6,4',6'-di-o-benzylidene-α,α'-D-trehalose

: 1448242-49-6
3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -78 ℃; for 3h; Inert atmosphere;
DOI:10.1021/jo4012255

Reference yield:

: 100-52-7
benzaldehyde

: 1448242-49-6
3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose

Guidance literature:: Multi-step reaction with 2 steps

1: iron(III) chloride hexahydrate; triethylsilane / dichloromethane; acetonitrile / 3 h / 20 °C / Cooling with ice; Inert atmosphere

2: 2,6-dimethylpyridine / dichloromethane / 3 h / -78 °C / Inert atmosphere

With 2,6-dimethylpyridine; triethylsilane; iron(III) chloride hexahydrate; In dichloromethane; acetonitrile;
DOI:10.1021/jo4012255

Reference yield:

: 42390-78-3
2,3,4,6,2',3',4',6'-octa-O-trimethylsilyl-α,α-D-trehalose

: 1448242-49-6
3,3′-di-O-benzyl-4,6;4′,6′-di-O-benzylidene-2′-O-tert-butyldimethylsilyl-α,α-D-trehalose

Guidance literature:: Multi-step reaction with 2 steps

1: iron(III) chloride hexahydrate; triethylsilane / dichloromethane; acetonitrile / 3 h / 20 °C / Cooling with ice; Inert atmosphere

2: 2,6-dimethylpyridine / dichloromethane / 3 h / -78 °C / Inert atmosphere

With 2,6-dimethylpyridine; triethylsilane; iron(III) chloride hexahydrate; In dichloromethane; acetonitrile;
DOI:10.1021/jo4012255