benzyl>dimethylamine

Base Information

• Chemical Name: benzyl>dimethylamine
• CAS No.: 41839-73-0
• Molecular Formula: C₁₃H₂₃NSi
• Molecular Weight: 221.418
• Mol file: 41839-73-0.mol

Synonyms:benzyl>dimethylamine

Chemical Property of benzyl>dimethylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of benzyl>dimethylamine

There total 4 articles about benzyl>dimethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

Benzyldimethyl<(trimethylsilyl)methyl>ammonium bromide (72443-52-8) → benzyl>dimethylamine (41839-73-0) + N,N-dimethyl-1-amino-1-phenyl-2-trimethylsilylethane (72443-66-4) + N,N-dimethyl-2-methyl-α-(trimethylsilyl)benzylamine (72443-56-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; 1.) 0-5 deg C, 3 h; 2.) room temperature, overnight.;

DOI:10.1021/jo01292a011

Reference yield:

chloro-trimethyl-silane (75-77-4) + N,N-dimethyl(2-methylbenzyl)amine (4525-48-8) → benzyl>dimethylamine (41839-73-0)

Guidance literature:

With n-butyllithium; triethylamine; Yield given. Multistep reaction; 1.) Et₂O, room temperatutre, 22 h, 2.) room temperature, 4 h;

DOI:10.1021/ja00390a036

Reference yield:

benzyltrimethylammonium iodide (4525-46-6) → benzyl>dimethylamine (41839-73-0)

Guidance literature:

Yield given. Multistep reaction; 1.) Sommelet rearrangement, 2.) silylation;

DOI:10.1021/ja00522a081

upstream raw materials:

Benzyldimethyl<(trimethylsilyl)methyl>ammonium bromide

benzyltrimethylammonium iodide

chloro-trimethyl-silane

N,N-dimethyl(2-methylbenzyl)amine

Downstream raw materials:

benzyl>trimethylammonium bromide

benzyl>dimethylamine

benzyl>dimethylamine

benzyl>acetate