Cupric tartrate

Base Information

• Chemical Name: Cupric tartrate
• CAS No.: 815-82-7
• Molecular Formula: C₄H₄O₆*Cu
• Molecular Weight: 211.618
• European Community (EC) Number: 248-162-3
• UN Number: 3077
• DSSTox Substance ID: DTXSID20949780
• Nikkaji Number: J1.569.539K
• Mol file: 815-82-7.mol

Synonyms:CUPRIC TARTRATE;Copper tartrate;27004-40-6;COPPERTARTRATE;EINECS 248-162-3;C4H6O6.xCu;C4-H6-O6.x-Cu;copper(II) tartrate;SCHEMBL119095;copper;2,3-dihydroxybutanedioate;DTXSID20949780;AKOS015901629;Copper(2+) 2,3-dihydroxybutanedioate

Chemical Property of Cupric tartrate

Chemical Property:

• Appearance/Colour: green to blue odorless powder
• Vapor Pressure: 4.93E-08mmHg at 25°C
• Melting Point: ~275 °C (dec.)(lit.)
• Boiling Point: 399.3 °C at 760 mmHg
• Flash Point: 209.4 °C
• PSA: 120.72000
• Density: 1.886 g/cm³
• LogP: -4.79450
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Water Solubility.: slightly soluble
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 210.930385
• Heavy Atom Count: 11
• Complexity: 123

Purity/Quality:

98%,99%, ^*data from raw suppliers

Copper(II) tartrate hydrate ^*data from reagent suppliers

Safty Information:

• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: C(C(C(=O)[O-])O)(C(=O)[O-])O.[Cu+2]

Technology Process of Cupric tartrate

There total 15 articles about Cupric tartrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

potassium sodium d-tartrate tetrahydrate (6381-59-5,28600-29-5,29116-26-5,57527-98-7,66516-21-0) + copper dichloride → copper(II) d-tartrate (815-82-7,3333-33-3,5020-95-1,13097-41-1,17263-56-8,23399-20-4,23482-65-7,27004-40-6)

Guidance literature:

In water; stirring (room temp., 1 h), standing overnight (pptn.); washing (water, methanol), drying (150°C, 1 Torr, 5 h); elem. anal.;

DOI:10.1246/bcsj.61.1213

Reference yield: 56.0%

tetrakis(acetato)diaquadicopper(II) + L-Tartaric acid (87-69-4,138508-61-9) → copper(II) L-tartrate (815-82-7,3333-33-3,5020-95-1,13097-41-1,17263-56-8,23399-20-4,23482-65-7,27004-40-6)

Guidance literature:

In water; byproducts: acetic acid; stoich. amts., refluxing for 3.5 h (periodical evapn. of AcOH); collection (hot filtration), washing (water, EtOH, ether), drying (vac.);

DOI:10.1016/S0277-5387(97)00100-9

Reference yield: 45.0%

tetrakis(acetato)diaquadicopper(II) + O,O'-dibenzoyl-L-tartaric acid (2743-38-6) → copper(II) L-tartrate (815-82-7,3333-33-3,5020-95-1,13097-41-1,17263-56-8,23399-20-4,23482-65-7,27004-40-6)

Guidance literature:

With water; In water; byproducts: acetic acid; stoich. amts., refluxing for 3.5 h (periodical evapn. of AcOH); collection (hot filtration), washing (water, EtOH, ether), drying (vac.);

DOI:10.1016/S0277-5387(97)00100-9

upstream raw materials:

Rochelle's salt

copper(II) sulfate

tartaric acid

sodium tartrate

Refernces

• 1、 Rodrigues, Emanuel C.,Carvalho, Claudio T.,de Siqueira, Adriano B.,Bannach, Gilbert,Ionashiro, Massao. "Synthesis, characterization and thermal behaviour on solid tartrates of some bivalent metal ions". . p. 156 - 160. Retrieved 2010/01/30.
• 2、 Weiss, Rainer,Vukojevi?, Sascha,Baltes, Christian,Naumann d'Alnoncourt, Raoul,Muhler, Martin,Epple, Matthias. "Copper/zinc L-tartrates: Mixed crystals and thermolysis to a mixture of copper oxide and zinc oxide that is catalytically active in methanol synthesis". . p. 4782 - 4786. Retrieved 2008/03/14.