iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride

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Chemical Name:iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride
CAS No.:99688-19-4
Molecular Formula:C₅₆H₄₉ClFeN₆O₂
Molecular Weight:929.344
Hs Code.:

Synonyms:iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride

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Chemical Property of iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride

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Technology Process of iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride

There total 1 articles about iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

: 99688-17-2
iron(III) 5-(2-carboxyphenyl)-10,15,20-tri-p-tolylporphyrin chloride

: 34272-83-8
2,2,5,5-tetramethyl-3-aminopyrrolidine-1-oxyl

: 99688-19-4
iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride

Guidance literature:: With pyridine; hydrogenchloride; oxalyl dichloride; In tetrahydrofuran; benzene; C2O2Cl2 added to soln. of Fe porphyrin in C6H6, evapd. after 4 h, dried in vac. for 3 h, redissolved in dry THF, pyridine and 3-amino-2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl added, refluxed under N2 for 12 h; evapd., dried (vac., 1 h), CHCl3 soln. washed with 0.01 M HCl, 0.01 M KOH, 0.02 M HCl, chromd. (SiO2, 2% MeOH/CHCl3), recrystd. (CHCl3/heptane), CHCl3 soln. shaken with 0.1 M KOH, chromd. (Al2O3, CHCl3), shaken with 0.03 HCl, pptd.(heptane), dried(vac.);
DOI:10.1021/ja00264a010

Reference yield:

: 288-32-4
1H-imidazole

: 99688-19-4
iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride

: {Fe(5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin)(imidazole)2}⁽¹⁺⁾

Guidance literature:: With hydrogenchloride; In chloroform; water; toluene; soln. of Fe porphyrin in toluene (1-5 mM) shaken with 0.05 M HCl, phases sepd., 10-fold or greater excess of imidazole (in CHCl3) added to org. phase; not isolated; detected by ESR;
DOI:10.1021/ja00264a010

Reference yield:

: 616-47-7
1-methyl-1H-imidazole

: 99688-19-4
iron(III) 5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin chloride

: {Fe(5-(2-(((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)amido)carbonyl)phenyl)-10,15,20-tri-p-tolylporphyrin)(1-methylimidazole)2}⁽¹⁺⁾

Guidance literature:: With hydrogenchloride; In chloroform; water; toluene; soln. of Fe porphyrin in toluene (1-5 mM) shaken with 0.05 M HCl, phases sepd., 10-fold or greater excess of 1-methylimidazole (in CHCl3) added to org. phase; not isolated; detected by ESR;
DOI:10.1021/ja00264a010