4-bromo-2-ethylphenyl allyl ether

Base Information

Chemical Name:4-bromo-2-ethylphenyl allyl ether
CAS No.:137206-65-6
Molecular Formula:C₁₁H₁₃BrO
Molecular Weight:241.128
Hs Code.:

Synonyms:4-bromo-2-ethylphenyl allyl ether

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Chemical Property of 4-bromo-2-ethylphenyl allyl ether

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 4-bromo-2-ethylphenyl allyl ether

There total 1 articles about 4-bromo-2-ethylphenyl allyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18980-21-7
4-bromo-2-ethylphenol

: 106-95-6
allyl bromide

: 137206-65-6
4-bromo-2-ethylphenyl allyl ether

Guidance literature:: With potassium tert-butylate; Yield given. Multistep reaction; 1) tert-butyl alcohol, reflux, o.5 h, 2) tert-butyl alcohol, reflux, 8 h;
DOI:10.1002/jhet.5570280535

Reference yield: 82.0%

: 137206-65-6
4-bromo-2-ethylphenyl allyl ether

: 137206-66-7
2-allyl-4-bromo-6-ethylphenol

Guidance literature:: With N,N-dimethyl-aniline; at 193 ℃; for 2.5h;
DOI:10.1002/jhet.5570280535

Reference yield:

: 137206-65-6
4-bromo-2-ethylphenyl allyl ether

: 60398-91-6
Bufuralol hydrochloride

Guidance literature:: Multi-step reaction with 12 steps

1: 82 percent / N,N-dimethylaniline / 2.5 h / 193 °C

2: 84 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 0 deg C to 22 deg C, 22 h

3: 75 percent / potassium hydroxide, water / dimethylsulfoxide / 3 h / 23 °C

4: 96 percent / triethylamine, 4-dimethylaminopyridine / CH₂Cl₂ / 8 h / 22 °C

5: 91 percent / N-bromosuccinimide, benzoylperoxide / CCl₄ / Heating; Irradiation

6: sodium cyanoborohydride, hexamethylphosphoramide / 10 h / 70 °C

7: 93 percent / potassium carbonate / methanol / 2 h / 22 °C

8: 81 percent / 2 M oxalyl chloride, dimethyl sulfoxide, triethylamine / CH₂Cl₂ / -60 °C

9: 1) sodium methylsulfinylmethide / 1) dimethyl sulfoxide, tetrahydrofuran, 0 deg C, 2 min, 2) tetrahydrofuran, 0 deg C, 30 min, then 24 deg C, 1 h

10: hexane; methanol / 14 h / Heating

11: hydrochloric acid / ethanol

12: 93 percent / hydrogen / 5 percent palladium on carbon / ethanol / 0.25 h / 775.7 Torr

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; potassium hydroxide; N-Bromosuccinimide; Perbenzoic acid; oxalyl dichloride; dimsylsodium; water; hydrogen; sodium cyanoborohydride; potassium carbonate; dimethyl sulfoxide; N,N-dimethyl-aniline; triethylamine; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; In methanol; tetrachloromethane; ethanol; hexane; dichloromethane; dimethyl sulfoxide;
DOI:10.1002/jhet.5570280535