2-allyl-4-bromo-6-ethylphenol

Base Information

Chemical Name:2-allyl-4-bromo-6-ethylphenol
CAS No.:137206-66-7
Molecular Formula:C₁₁H₁₃BrO
Molecular Weight:241.128
Hs Code.:

Synonyms:2-allyl-4-bromo-6-ethylphenol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-allyl-4-bromo-6-ethylphenol

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Technology Process of 2-allyl-4-bromo-6-ethylphenol

There total 2 articles about 2-allyl-4-bromo-6-ethylphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 137206-65-6
4-bromo-2-ethylphenyl allyl ether

: 137206-66-7
2-allyl-4-bromo-6-ethylphenol

Guidance literature:: With N,N-dimethyl-aniline; at 193 ℃; for 2.5h;
DOI:10.1002/jhet.5570280535

Reference yield:

: 18980-21-7
4-bromo-2-ethylphenol

: 137206-66-7
2-allyl-4-bromo-6-ethylphenol

Guidance literature:: Multi-step reaction with 2 steps

1: 1) potassium tert-butoxide / 1) tert-butyl alcohol, reflux, o.5 h, 2) tert-butyl alcohol, reflux, 8 h

2: 82 percent / N,N-dimethylaniline / 2.5 h / 193 °C

With potassium tert-butylate; N,N-dimethyl-aniline;
DOI:10.1002/jhet.5570280535

Reference yield:

: 137206-66-7
2-allyl-4-bromo-6-ethylphenol

: 60398-91-6
Bufuralol hydrochloride

Guidance literature:: Multi-step reaction with 11 steps

1: 84 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 0 deg C to 22 deg C, 22 h

2: 75 percent / potassium hydroxide, water / dimethylsulfoxide / 3 h / 23 °C

3: 96 percent / triethylamine, 4-dimethylaminopyridine / CH₂Cl₂ / 8 h / 22 °C

4: 91 percent / N-bromosuccinimide, benzoylperoxide / CCl₄ / Heating; Irradiation

5: sodium cyanoborohydride, hexamethylphosphoramide / 10 h / 70 °C

6: 93 percent / potassium carbonate / methanol / 2 h / 22 °C

7: 81 percent / 2 M oxalyl chloride, dimethyl sulfoxide, triethylamine / CH₂Cl₂ / -60 °C

8: 1) sodium methylsulfinylmethide / 1) dimethyl sulfoxide, tetrahydrofuran, 0 deg C, 2 min, 2) tetrahydrofuran, 0 deg C, 30 min, then 24 deg C, 1 h

9: hexane; methanol / 14 h / Heating

10: hydrochloric acid / ethanol

11: 93 percent / hydrogen / 5 percent palladium on carbon / ethanol / 0.25 h / 775.7 Torr

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; potassium hydroxide; N-Bromosuccinimide; Perbenzoic acid; oxalyl dichloride; dimsylsodium; water; hydrogen; sodium cyanoborohydride; potassium carbonate; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; palladium on activated charcoal; In methanol; tetrachloromethane; ethanol; hexane; dichloromethane; dimethyl sulfoxide;
DOI:10.1002/jhet.5570280535