μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Chemical Name:μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)
CAS No.:220355-79-3
Molecular Formula:C₉₆H₁₀₀I₂N₈Zn₂
Molecular Weight:1750.49
Hs Code.:

Synonyms:μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Chemical Property of μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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Technology Process of μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

There total 1 articles about μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 187387-16-2
μ-[10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 220355-79-3
μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Guidance literature:: With AgPF₆; In pyridine; chloroform; acetonitrile; N2 atm.; a soln. of AgPF6 in dry CH3CN was added at 25°C to a soln. of complex and I2 in CHCl3/pyridine 30:1, the mixt. was stirred for 11 min; quenched with H2O, the organic layer was diluted with CHCl3, washed withH2O, satd. aq. NaCl, dried (Na2SO4), evapd. in vac., flash chromy. (sil ica gel; cyclohexane/CH2Cl2 7:3, 1% v/v (C2H5)3N), pptn. from CH2Cl2 upon addn. of CH3OH;
DOI:10.1002/hlca.200590144

Reference yield: 90.0%

: 220355-79-3
μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 495402-49-8
2-[3-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 495413-29-1
(Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In toluene; mixt. refluxed in C6H5CH3 for 18 h;
DOI:10.1039/b206624f

Reference yield: 69.0%

: 220355-79-3
μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 214360-46-0
3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile

: 637765-04-9
μ-[15,15'-bis(3-cyanophenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

: 866321-93-9
μ-[15-(3-cyanophenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Guidance literature:: With Cs₂CO₃; H₂O; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; N2 atm.; to a soln. of complex in toluene borolane-compound, Pd(P(C6H5)3)4, Cs2CO3 and three drops of H2O were added, the mixt. was deoxygenatedby bubbling N2, stirred at 100°C for 18 h, cooled to 25°C; filtered through Celite, evapd. in vac.; flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1, 1% v/v (C2H5)3N), pptn. with methanol/H2O 9:1 from CHCl3-soln.;
DOI:10.1002/hlca.200590144