Sodium formaldehyde bisulfite

Base Information

• Chemical Name: Sodium formaldehyde bisulfite
• CAS No.: 870-72-4
• Deprecated CAS: 133915-55-6,144233-13-6,180915-17-7,2053-10-3,2152-08-1,53743-83-2,57523-69-0,260368-63-6,1032191-55-1,1032191-55-1,144233-13-6,180915-17-7,2053-10-3,2152-08-1,260368-63-6,53743-83-2
• Molecular Formula: CH3NaO4S
• Molecular Weight: 134.088
• Hs Code.: 29055900
• European Community (EC) Number: 212-800-9
• UNII: I566KHA05F
• DSSTox Substance ID: DTXSID3027328
• Nikkaji Number: J57.764B
• Wikidata: Q27280467
• ChEMBL ID: CHEMBL3185494
• Mol file: 870-72-4.mol

Synonyms:Methanesulfonicacid, hydroxy-, monosodium salt (8CI,9CI);Methanesulfonic acid, hydroxy-,sodium salt (6CI);Hydroxymethanesulfonic acid sodium salt;Monosodiumhydroxymethanesulfonate;Sodium formaldehyde bisulfite;Sodiumhydroxymethanesulfonate;Sodium hydroxymethylsulfonate;

Chemical Property of Sodium formaldehyde bisulfite

Chemical Property:

• Appearance/Colour: white to almost white powder
• Melting Point: 200 °C (dec.)(lit.)
• Boiling Point: 184 °C
• Flash Point: 184 °C
• PSA: 85.81000
• LogP: -0.43780
• Storage Temp.: -20°C
• Sensitive.: Hygroscopic
• Solubility.: Methanol (Slightly, Heated), Water (Slightly)
• Water Solubility.: 800 g/L (20 ºC)
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 133.96497403
• Heavy Atom Count: 7
• Complexity: 108

Purity/Quality:

98% ^*data from raw suppliers

Formaldehyde Sodium Bisulfite ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: C(O)S(=O)(=O)[O-].[Na+]
• Uses: Formaldehyde Sodium Bisulfite is used in the preparation of oil-soluble sulfonate additives used in improving anticorrosive, dispersant and antioxygenic properties of lubricant oils. Also used in chemical reactions in the preparation of chiral salen Mn(III) catalysts or lignosulfonates as dispersant for gypsum paste. Formaldehyde sodium bisulfite, is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff. It also acts as an pharmaceutical intermediate. It can effectively complex metal ion such as Cu, Zn, Pb, co-depositing with nickel ion.

Technology Process of Sodium formaldehyde bisulfite

There total 10 articles about Sodium formaldehyde bisulfite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

p-chloroanilinomethanesulfonate (56638-59-6) → sodium formaldehyde bisulfite (870-72-4) + 4-chloro-aniline (106-47-8)

Guidance literature:

With water; Equilibrium constant; Rate constant; Thermodynamic data; Ambient temperature; also formation constants;

Reference yield:

p-methylanilinomethanesulfonate (56638-52-9) → sodium formaldehyde bisulfite (870-72-4) + p-toluidine (106-49-0,12221-03-3)

Guidance literature:

With water; Equilibrium constant; Rate constant; Thermodynamic data; Ambient temperature; also formation constants;

Reference yield:

m-chloroanilinomethanesulfonate (56638-60-9) → sodium formaldehyde bisulfite (870-72-4) + 3-chloro-aniline (108-42-9)

Guidance literature:

With water; Equilibrium constant; Rate constant; Thermodynamic data; Ambient temperature; also formation constants;

upstream raw materials:

formaldehyd

p-methylanilinomethanesulfonate

p-chloroanilinomethanesulfonate

p-methoxyanilinomethanesulfonate

Downstream raw materials:

sulfurous acid mono-diethylaminomethyl ester

(4,4'-sulfonyl-dianilino)-bis-methanesulfonic acid ; sodium-salt

Sodium; (2-hydroxy-5-methyl-phenyl)-methanesulfonate

p-chloroanilinomethanesulfonate

Refernces

• 1、 Atherton, John H.,Brown, Kathryn H.,Crampton, Michael R.. "A mechanistic study of the reactions of formaldehyde with aniline in the presence of sulfite". . p. 941 - 946. Retrieved 2007/10/03.
• 2、 King, J. F.,Skonieczny, S.. "TRIMETHYLAMMONIOMETHANESULFINATE AND TRIMETHYLAMMONIOMETHANESULFONATE, THE SIMPLEST SULFINIC AND SULFONIC ACID BETAINES. REVISION OF THE STRUCTURE OF THE TRIMETHYLAMINE OXIDE-SULFUR DIOXIDE PRODUCT". . p. 11 - 20. Retrieved 2007/10/02.