trimethylphosphine-triborane adduct

Base Information

• Chemical Name: trimethylphosphine-triborane adduct
• CAS No.: 97012-38-9
• Molecular Formula: C₃H₁₆B₃P
• Molecular Weight: 115.567
• Mol file: 97012-38-9.mol

Synonyms:trimethylphosphine-triborane adduct

Chemical Property of trimethylphosphine-triborane adduct

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trimethylphosphine-triborane adduct

There total 6 articles about trimethylphosphine-triborane adduct which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(B3H6N(CH3)3P(CH3)3)(1+)*B2H7(1-)=(B3H6N(CH3)3P(CH3)3)B2H7 (112968-02-2) → B3H7P(CH3)3 (97012-38-9) + trimethylamine-borane (75-22-9)

Guidance literature:

In dichloromethane; byproducts: B2H6; Quantitative decompn. of B3H6NMe3PMe3*B2H7 above 0°C.;

Reference yield:

trimethylphosphine-tetraborane adduct (71749-92-3) → trimethylphosphine-triborane adduct (97012-38-9) + B2H5Cl + boron trichloride (10294-34-5) + diborane (19287-45-7)

Guidance literature:

With hydrogenchloride; In dichloromethane; B-complex was reacted with HCl at -80°C in CH2Cl2;

Reference yield:

tetraborane (18283-93-7) + trimethylphosphane (594-09-2) → borane-THF (14044-65-6) + octahydrotriborate(1-) + trimethylphosphine-triborane adduct (97012-38-9) + triborane(7)*tetrahydrofuran + trimethylphosphine-borane (1898-77-7)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; dichloromethane; B4H10 dissolved in THF at -80°C, kept at 0°C for 4 h, treated with PMe3 in CH2Cl2 at 25°C; NMR anal.;

upstream raw materials:

trimethylphosphine-borane

tetraborane

diethyl ether

trimethylphosphane

Downstream raw materials:

pentaborane⁽⁹⁾

trimethylphosphine-borane

trimethylamine-trimethylphosphine-diborane⁽⁴⁾

trimethylamine-borane