4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide

Base Information

• Chemical Name: 4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide
• CAS No.: 58971-25-8
• Molecular Formula: C₁₀H₁₈N₂O₂SSi
• Molecular Weight: 258.417
• Mol file: 58971-25-8.mol

Synonyms:4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide

Chemical Property of 4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide

There total 1 articles about 4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N-Dimethyltrimethylsilylamine (2083-91-2) + toluene-4-sulfonic acid hydrazide (1576-35-8) → 4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide (58971-25-8)

Guidance literature:

In benzene;

Reference yield: 95.0%

4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide (58971-25-8) → tris(trimethylsilyl)hydrazine (13272-02-1) + p-toluenesulfinic acid lithium salt (16844-27-2) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; at 140 ℃; under 0.2 Torr; Product distribution;

DOI:10.1021/jo01303a038

Reference yield: 64.0%

4-methylbenzenesulfonic acid 1-(trimethylsilyl)hydrazide (58971-25-8) → trimethylsilyl 4-methylbenzenesulfinate (72784-68-0)

Guidance literature:

at 170 ℃; under 0.1 Torr;

DOI:10.1021/jo01303a038

upstream raw materials:

N,N-Dimethyltrimethylsilylamine

toluene-4-sulfonic acid hydrazide

Downstream raw materials:

diphenylmethyl trimethylsilyl ether

p-toluenesulfinic acid lithium salt

p-toluene sulfinic acid

(trimethylsilyl)diazene