Methyl camphorate, (+)-

Base Information

Chemical Name:Methyl camphorate, (+)-
CAS No.:29607-02-1
Molecular Formula:C₁₁H₁₈O₄
Molecular Weight:214.262
Hs Code.:
UNII:2U0ZVS444U
Nikkaji Number:J1.023.985K
Wikidata:Q27255593

Synonyms:Methyl camphorate, (+)-;29607-02-1;Methyl camphorate, (1R,3S)-;3-Methyl (1R,3S)-(+)-camphorate;2U0ZVS444U;(1R,3S)-3-(methoxycarbonyl)-1,2,2-trimethylcyclopentanecarboxylic acid;(1R,3S)-3-methoxycarbonyl-1,2,2-trimethylcyclopentane-1-carboxylic acid;(1R,3S)-3-(Methoxycarbonyl)-1,2,2-trimethylcyclopentane-1-carboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, 3-methyl ester, cis-(+)-;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, 3-methyl ester, (1R,3S)-;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, 3-methyl ester, (1R-cis)-;26252-15-3;UNII-2U0ZVS444U;(+)-methyl camphorate;starbld0008223;SCHEMBL2534532;VFNNTVXOZWMVGX-HQJQHLMTSA-N;AKOS037503935;EN300-7544968;Q27255593

Suppliers and Price of Methyl camphorate, (+)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Methyl camphorate, (+)-

Chemical Property:

XLogP3:1.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:214.12050905
Heavy Atom Count:15
Complexity:295

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(C(CCC1(C)C(=O)O)C(=O)OC)C
Isomeric SMILES:C[C@]1(CC[C@@H](C1(C)C)C(=O)OC)C(=O)O

Technology Process of Methyl camphorate, (+)-

There total 2 articles about Methyl camphorate, (+)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67-56-1
methanol

: 76-32-4
(±)-camphoric acid anhydride

: 26252-15-3,26252-19-7,29606-91-5,29606-95-9,29607-02-1,29722-60-9
(+/-)-3-methyl hydrogen 1,2,2-trimethyl-cis-1,3-cyclopentanedicarboxylate

: 26252-16-4,26252-20-0,29606-94-8,29606-98-2,29606-99-3,29722-59-6
(+/-)-3-methyl hydrogen 2,2,3-trimethyl-cis-1,3-cyclopentanedicarboxylate

Guidance literature:: for 48h; Title compound not separated from byproducts; Heating;
DOI:10.1139/v88-009

Reference yield:

: 67-56-1
methanol

: 6053-45-8
2,2-dimethyl-cyclopentane-1,1,3-tricarboxylic acid

: 7282-27-1,16089-19-3,29606-96-0
1,2,2-trimethyl-cyclopentane-1,3-dicarboxylic acid dimethyl ester

: 29607-02-1
(1R,3S)-3-(methoxycarbonyl)-1,2,2-trimethylcyclopentanecarboxylic acid

Guidance literature:: With hydrogenchloride;

Reference yield: 51.0%

: 271-89-6
1-benzofurane

: 1942-46-7
5-decyne

: 29607-02-1
(1R,3S)-3-(methoxycarbonyl)-1,2,2-trimethylcyclopentanecarboxylic acid

: 1-((E)-6-(benzofuran-2-yl)dec-5-en-5-yl) 3-methyl (1R,3S)-1,2,2-trimethylcyclopentane-1,3-dicarboxylate

Guidance literature:: With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; 2,2',3,3',4,4',5,5',6,6'-Decabromodiphenyl ether; oxygen; copper (I) acetate; In decane; water; at 23 - 140 ℃; for 3.5h; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201409450