5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten

Base Information

• Chemical Name: 5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten
• CAS No.: 106710-91-2
• Molecular Formula: C₂₆H₆₀N₄Si₃
• Molecular Weight: 513.046
• Mol file: 106710-91-2.mol

Synonyms:5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten

Chemical Property of 5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten

There total 3 articles about 5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

tri-t-butylsilyl azide (69322-38-9) + 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan (80431-36-3) → diphenylmethyleneaminotrimethylsilane (17599-59-6) + bis(trimethylsilyl)diazomethane (30006-66-7) + 5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten (106710-91-2)

Guidance literature:

In diethyl ether; at 100 ℃; for 6h; Yields of byproduct given;

Reference yield: 60.0%

tri-t-butylsilyl azide (69322-38-9) + Brom(bromdiphenylsilyl)bis(trimethylsilyl)methan (117984-10-8) → bis(trimethylsilyl)diazomethane (30006-66-7) + 5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten (106710-91-2) + C17H22N2Si2 + 5,5-Diphenyl-1,4-bis-tri-tert-butylsilanyl-4,5-dihydro-1H-[1,2,3,4,5]tetrazasilole

Guidance literature:

With phenyllithium; In diethyl ether; benzene; for 15h; Ambient temperature;

Reference yield:

tri-t-butylsilyl azide (69322-38-9) + 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan (80431-36-3) → diphenylmethyleneaminotrimethylsilane (17599-59-6) + 5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten (106710-91-2)

Guidance literature:

In diethyl ether; at 100 ℃; for 12h;

upstream raw materials:

tri-t-butylsilyl azide

2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan

Brom(bromdiphenylsilyl)bis(trimethylsilyl)methan

Downstream raw materials:

tri-t-butylsilyl azide

(tri-tert-butylsilyl)amin

1-chloro-1,1,3,3,3-pentamethyldisiloxane

2,2,4,4-tetramethy-1-tri-t-butylsilyl-3-oxa-1-aza-2,4-disilacyclobutan