80431-36-3

Basic information

• Product Name: 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan
• Synonyms: 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan
• CAS NO: 80431-36-3
• Molecular Weight: 469.965
• Mol File: 80431-36-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan(80431-36-3)
• EPA Substance Registry System: 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan(80431-36-3)

Safety Data

• Hazardous Substances Data: 80431-36-3(Hazardous Substances Data)

Upstream product

• 17599-59-6 diphenylmethyleneaminotrimethylsilane 
• 78907-38-7 Brom(fluordimethylsilyl)bis(trimethylsilyl)methan 
• 80431-44-3 2,3,4,4a-Tetrahydro-3,3-dimethyl-1-phenyl-2,4,4-tris(trimethylsilyl)-2-aza-3-silanaphthalin 
• 62139-74-6 Brom(bromdimethylsilyl)bis(trimethylsilyl)methan 

Downstream Products

• 2943-62-6 1-chloro-1,1,3,3,3-pentamethyldisiloxane 
• 17599-59-6 diphenylmethyleneaminotrimethylsilane 
• 30006-66-7 bis(trimethylsilyl)diazomethane 
• 80431-48-7 (trimethylsilyl)diazomethan 
• 80431-42-1 4,4a-dihydro-3,3-dimethyl-1-phenyl-4,4-bis(trimethylsilyl)-3H-2-oxa-3-silanaphthaline 
• 80431-43-2 2,2-Dimethyl-4,4-diphenyl-3,3-bis(trimethylsilyl)-1-oxa-2-silacyclobutan 
• 109308-40-9 1,1-Dimethyl-2,2-bis(trimethylsilyl)-3-(cis-1'-methylvinyl)-1-silacyclobutan 
• 108148-89-6 silyl>(trimethylsilyl)diazomethan 
• 78375-55-0 1,1-bis(trimethylsilyl)-2,2-diphenylethylene 
• 80431-44-3 2,3,4,4a-Tetrahydro-3,3-dimethyl-1-phenyl-2,4,4-tris(trimethylsilyl)-2-aza-3-silanaphthalin 
• 80431-45-4 N-silyl>benzophenonimin 
• 106710-91-2 5,5-Dimethyl-1,4-bis(tri-tert-butylsilyl)-1,2,3,4-tetraaza-5-sila-2-cyclopenten 
• 1013-88-3 Benzophenone imine 
• 1825-64-5 isopropoxytrimethylsilane 

Relevant articles and documents

On the reactivity of silaethene Me2Si=C(SiMe3)2: Regioselectivity, stereoselectivity and relative rates of ene reactions [1]

Ene reactions of Me2Si=C(SiMe3)2 (1) with propene or with methyl derivatives of propene and 1,3-butadiene, respectively, of the formula R1CH=CR2-CH2R3 take place regioselectively, as well as stereoselectively and are retarded by increasing bulk of R1, R3 (for example H 3 2 2 to donate electrons (for example H 3 ≈ CH=CH2 2SiMe2[CH(SiMe3)2]). It is concluded from these studies, that ene reactions of 1 occur concerted and are HOMOene-LUMOenophile controlled.

Reaktivitaet des Silaethens Me2Si=C(SiMe3)2: Thermolyse von (Me3Si)2(Me2XSi)CLi (X z. B. (PhO)2PO2) in Anwesenheit von Silaethen-Faengern

Silaethene Me2Si=C(SiMe3)2 (1), generated as a reaction intermediate by the thermal elimination of LiX from Me2XSi-CLi(SiMe3)2, combines with the reactants a - b (e. g.Me3Si-Cl, Me3Si-OMe) with insertion in the a - b bond, with a = b - c - H (e. g.CH2=CMe