chloro(phenylphosphine)(acetonitrile)carbonylbis(triphenylphosphine)osmium(II) perchlorate

Base Information

Chemical Name:chloro(phenylphosphine)(acetonitrile)carbonylbis(triphenylphosphine)osmium(II) perchlorate
CAS No.:102849-33-2
Molecular Formula:C₄₅H₄₀ClNOOsP₃*ClO₄
Molecular Weight:1028.84
Hs Code.:

Synonyms:chloro(phenylphosphine)(acetonitrile)carbonylbis(triphenylphosphine)osmium(II) perchlorate

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Chemical Property of chloro(phenylphosphine)(acetonitrile)carbonylbis(triphenylphosphine)osmium(II) perchlorate

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Technology Process of chloro(phenylphosphine)(acetonitrile)carbonylbis(triphenylphosphine)osmium(II) perchlorate

There total 1 articles about chloro(phenylphosphine)(acetonitrile)carbonylbis(triphenylphosphine)osmium(II) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 102849-31-0
hydridochloro(phenylphosphine)carbonylbis(triphenylphosphine)osmium(II)

: 75-05-8,26809-02-9
acetonitrile

: 102849-33-2
chloro(phenylphosphine)(acetonitrile)carbonylbis(triphenylphosphine)osmium(II) perchlorate

Guidance literature:: With perchloric acid; In dichloromethane; acetonitrile; byproducts: H2; inert atmosphere; addn. of HClO4 in CH3CN) to Os-complex in CH2Cl2; stirring for 2.5 h;; removal of solvent under vac.; dissolving in CH2Cl2 and recrystn. with 2-propanol; elem. anal.;

Reference yield: 97.0%

: 102849-33-2
chloro(phenylphosphine)(acetonitrile)carbonylbis(triphenylphosphine)osmium(II) perchlorate

: 638-21-1
phenylphosphane

: 102747-27-3
chlorobis(phenylphosphine)carbonylbis(triphenylphosphine)osmium(II) perchlorate

Guidance literature:: In chloroform; benzene; inert atmosphere; addn. of PH2Ph in C6H6 to soln. of Os-complex in CHCl3; refluxing at 62°C for 24 h;; cooling; removal of volatiles under vac.; recrystn. from CH2Cl2/EtOH; elem. anal.;

Reference yield: 96.0%

: 102849-33-2
{OsCl(PH₂Ph)(NCCH₃)(CO)(PPh₃)2}ClO₄

: 7175-47-5
4-methylphenyl isocyanide

: 116890-86-9
{OsCl(PH₂Ph)(CN-p-tolyl)(CO)(PPh₃)2}ClO₄

Guidance literature:: In dichloromethane; OsCl(PH2C6H5)(NCCH3)(CO)(PPh3)2ClO4 and p-tolylisocyanide stirred for 10 h in CH2Cl2 at 25°C, then ethanol and isopropanol added.; washing with hexane; elem. anal.;
DOI:10.1016/0022-328X(88)80421-2