trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate

Base Information

Chemical Name:trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate
CAS No.:334543-31-6
Molecular Formula:BF₄*C₄₆H₄₆IrN₂OP₂
Molecular Weight:983.856
Hs Code.:

Synonyms:trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate

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Chemical Property of trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate

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Technology Process of trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate

There total 3 articles about trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: cis,trans-[dihydridobis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-ylidene)iridium(III)] fluoroborate diethyl ether solvate

: 67-64-1
acetone

: 334543-31-6
trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate

Guidance literature:: In acetone; (Ar or N2); using Schlenk techniques; addn. of py-NMe2 to acetone soln. of (H2Ir(PPh3)2(C5H4NNMeCH))(BF4);
DOI:10.1021/ja048473j

Reference yield: 65.0%

: 5683-33-0
2-(Dimethylamino)pyridine

: 38834-40-1
bis(triphenylphosphine)(cycloocta-1,5-diene)iridium(I) tetrafluoroborate

: 1333-74-0
hydrogen

: 67-64-1
acetone

: 334543-31-6
trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate

Guidance literature:: In acetone; (Ar or N2); using Schlenk techniques; addn. of py-NMe2 via syringe to acetone soln. of (Ir(COD)(PPh3)2)(BF4); passing H2 gas for 10 min at 0°C; addn. of Et2O; pptn., filtration, washing with Et2O; drying in vac., recrystn. from CH2Cl2/Et2O;
DOI:10.1021/ja048473j

Reference yield: 37.0%

: 5683-33-0
2-(Dimethylamino)pyridine

: 82582-67-0,72414-17-6
[Ir(hydrido)2(acetone)2(triphenylphosphine)2](BF4)

: 334543-31-6
trans-[hydrido(acetone)bis(triphenylphosphine)(N,C-2-(dimethylamino)pyridine-1'-yl)iridium(III)] fluoroborate

Guidance literature:: In acetone; (Ar or N2); using Schlenk techniques; addn. of py-NMe2 to acetone soln. of (H2Ir(OCMe2)2(PPh3)2)(BF4); stirring for 15 min; addn. of Et2O, pptn., washing with Et2O, drying in vac.;
DOI:10.1021/ja048473j