3-(prop-2-en-1-yl)cyclohexene

Base Information

• Chemical Name: 3-(prop-2-en-1-yl)cyclohexene
• CAS No.: 15232-95-8
• Molecular Formula: C9H14
• Molecular Weight: 122.21
• Mol file: 15232-95-8.mol

Synonyms:Cyclohexene,3-(2-propenyl)- (9CI); Cyclohexene, 3-allyl- (7CI,8CI); 3-Allyl-1-cyclohexene;3-Allylcyclohexene; 3-Allylcyclohexene-1

Chemical Property of 3-(prop-2-en-1-yl)cyclohexene

Chemical Property:

• Vapor Pressure: 5.01mmHg at 25°C
• Boiling Point: 149.9°C at 760 mmHg
• Flash Point: 29°C
• PSA: 0.00000
• Density: 0.82g/cm³
• LogP: 2.91880

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-(prop-2-en-1-yl)cyclohexene

There total 7 articles about 3-(prop-2-en-1-yl)cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

rac-3-bromocyclohexene (1521-51-3,113667-32-6) + allylmagnesium bromide (1730-25-2) → cyclohexene,3-(2-propenyl)- (15232-95-8)

Guidance literature:

In diethyl ether; at 20 ℃; for 1.66h; Inert atmosphere; Cooling with ice; Glovebox;

DOI:10.1021/ja504414c

Reference yield: 83.0%

Cyclohex-2-enol (822-67-3) + allyl-trimethyl-silane (762-72-1) → cyclohexene,3-(2-propenyl)- (15232-95-8)

Guidance literature:

With titanium tetrachloride; In dichloromethane; at 20 ℃; for 0.166667h;

DOI:10.1055/s-0033-1338746

Reference yield: 74.0%

rac-3-bromocyclohexene (1521-51-3,113667-32-6) + allyl-trimethyl-silane (762-72-1) → cyclohexene,3-(2-propenyl)- (15232-95-8)

Guidance literature:

With silver trifluoromethanesulfonate; In acetonitrile; at 0 ℃; for 1h; chemoselective reaction;

DOI:10.1021/acs.joc.1c00480

upstream raw materials:

rac-3-bromocyclohexene

allylmagnesium bromide

cyclohex-2-en-1-yl 2,4,6-trimethylbenzoate

acetic acid

Downstream raw materials:

3-cyclohex-2-en-1-ylpropan-1-ol

3-triphenylmethyl-5-<(2-cyclohexen-1-yl)methyl>-2-isoxazoline

3-acetoxy-6-(2-propenyl)cyclohexene

3-(1-acetoxy-2-propenyl)cyclohexene