(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Mn(II)Cl₂

Base Information

• Chemical Name: (2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Mn(II)Cl₂
• CAS No.: 221391-06-6
• Molecular Formula: C₃₃H₄₃Cl₂MnN₃
• Molecular Weight: 607.569
• Mol file: 221391-06-6.mol

Synonyms:(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Mn(II)Cl₂

Chemical Property of (2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Mn(II)Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Mn(II)Cl₂

There total 1 articles about (2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Mn(II)Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine (204203-14-5) + [MnCl2(tetrahydrofuran)2] (70317-52-1) → (2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Mn(II)Cl2 (221391-06-6)

Guidance literature:

In toluene; soln. of ligand in toluene treated with 1 equiv. of Mn complex; heated under reflux overnight; evapd. to dryness; residue dissolved in CH2Cl2; filtered; soln. layered with hexane; crystn. over 2 wk; elem. anal.;

DOI:10.1021/om0110078

Reference yield: 92.0%

diethyl ether (60-29-7,927820-24-4) + dichloro(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)manganese(II) (221391-06-6) + carbon monoxide (201230-82-2) + sodium (7440-23-5) → [((i-Pr)PDI)Mn(CO)2][Na(Et2O)3]

Guidance literature:

With Na(Hg); In toluene; byproducts: NaCl; N2; Na (9.87 mmol) added to Hg (226.38 mmol) in toluenepentane, stirred for 10 min, Mn compd. (1.65 mmol) added, mixt. cooled (liquid N2), CO (4atm) added, warmed to room temp. and stirred for 48 h; decanted, filtered (Celite), extd. (Et2O), filtered (Celite), crystd. onstorage at -35°C, elem. anal.;

DOI:10.1002/ejic.201100569

Reference yield: 91.0%

dichloro(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)manganese(II) (221391-06-6) + ((i-Pr)PDI)Mn(THF)2 → ((i-Pr)PDI)Mn(THF)Cl

Guidance literature:

In tetrahydrofuran; N2; 1:1 mixt. in THF stirred for 16 h; evapd., extd. (Et2O), filtered (Celite), evapd., elem. anal.;

DOI:10.1002/ejic.201100569

upstream raw materials:

N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine

[MnCl₂(tetrahydrofuran)₂]

Downstream raw materials:

manganese

(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)Mn(I)CH₃

(2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine)bis(triflato)manganese(II)

[[(C₃H₇)2C₆H₃NCCH₃](C₅H₃N)[(C₃H₇)2C₆H₃NCCH₂]]2(MnCH₂Si(CH₃)3)2