Technology Process of C15H24O3Si
There total 4 articles about C15H24O3Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
lithium aluminium tetrahydride;
In
diethyl ether;
at -78 - 20 ℃;
for 11h;
optical yield given as %ee;
chemoselective reaction;
Inert atmosphere;
DOI:10.1021/ol301191u
- Guidance literature:
-
Multi-step reaction with 3 steps
1: allyl(cyclopentadiene)palladium(II); C38H42NO2P / toluene / 14 h / 10 °C
2: 20% palladium hydroxide on charcoal; hydrogen / dichloromethane / 12 h / 0 °C / 760.05 Torr / Inert atmosphere
3: lithium aluminium tetrahydride / diethyl ether / 11 h / -78 - 20 °C / Inert atmosphere
With
lithium aluminium tetrahydride; allyl(cyclopentadiene)palladium(II); 20% palladium hydroxide on charcoal; C38H42NO2P; hydrogen;
In
diethyl ether; dichloromethane; toluene;
DOI:10.1021/ol301191u
- Guidance literature:
-
Multi-step reaction with 4 steps
1: tetrahydrofuran; diethyl ether / 38.5 h / 0 - 35 °C / Inert atmosphere
2: allyl(cyclopentadiene)palladium(II); C38H42NO2P / toluene / 14 h / 10 °C
3: 20% palladium hydroxide on charcoal; hydrogen / dichloromethane / 12 h / 0 °C / 760.05 Torr / Inert atmosphere
4: lithium aluminium tetrahydride / diethyl ether / 11 h / -78 - 20 °C / Inert atmosphere
With
lithium aluminium tetrahydride; allyl(cyclopentadiene)palladium(II); 20% palladium hydroxide on charcoal; C38H42NO2P; hydrogen;
In
tetrahydrofuran; diethyl ether; dichloromethane; toluene;
DOI:10.1021/ol301191u
