251453-07-3 Usage
Uses
Used in Organic Synthesis:
1-(4-Methoxyphenyl)-1-chlorosilacyclobutane is used as a reagent or intermediate in the synthesis of various organic compounds. Its unique reactivity and physical properties make it a valuable component in the development of new chemical reactions and the production of complex organic molecules.
Used in Materials Science:
In the field of materials science, 1-(4-Methoxyphenyl)-1-chlorosilacyclobutane is used as a precursor for the development of new materials with specific properties. Its organosilicon nature allows for the creation of materials with enhanced thermal stability, mechanical strength, and other desirable characteristics.
Used in Pharmaceutical Research:
1-(4-Methoxyphenyl)-1-chlorosilacyclobutane is used as a building block or a key intermediate in the synthesis of pharmaceutical compounds. Its unique structure and reactivity can contribute to the development of new drugs with improved efficacy and selectivity.
Used in Electronics:
In the electronics industry, 1-(4-Methoxyphenyl)-1-chlorosilacyclobutane may be used in the development of new electronic materials, such as semiconductors, insulators, or conductive polymers. Its organosilicon nature can provide unique electronic properties that can be harnessed for various applications.
Used in Surface Coatings:
1-(4-Methoxyphenyl)-1-chlorosilacyclobutane is used as a component in the formulation of surface coatings, such as paints, varnishes, or adhesives. Its organosilicon properties can contribute to improved durability, resistance to environmental factors, and adhesion to various substrates.
Check Digit Verification of cas no
The CAS Registry Mumber 251453-07-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,5,1,4,5 and 3 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 251453-07:
(8*2)+(7*5)+(6*1)+(5*4)+(4*5)+(3*3)+(2*0)+(1*7)=113
113 % 10 = 3
So 251453-07-3 is a valid CAS Registry Number.
InChI:InChI=1/C10H13ClOSi/c1-12-9-3-5-10(6-4-9)13(11)7-2-8-13/h3-6H,2,7-8H2,1H3
251453-07-3Relevant articles and documents
Palladium-catalyzed desymmetrization of silacyclobutanes with alkynes: Enantioselective synthesis of silicon-stereogenic 1-sila-2-cyclohexenes and mechanistic considerations
Shintani, Ryo,Moriya, Kohei,Hayashi, Tamio
supporting information; experimental part, p. 2902 - 2905 (2012/07/17)
A palladium-catalyzed enantioselective desymmetrization of silacyclobutanes with alkynes has been developed to give silicon-stereogenic 1-sila-2-cyclohexenes with high enantioselectivity. The products thus obtained undergo further derivatizations with complete stereoselectivity, and a new catalytic cycle involving alkyne coordination (oxidative cyclization)- transmetalation (σ-bond metathesis)-reductive elimination has also been proposed.
Palladium-catalyzed enantioselective desymmetrization of silacyclobutanes: Construction of silacycles possessing a tetraorganosilicon stereocenter
Shintani, Ryo,Moriya, Kohei,Hayashi, Tamio
supporting information; experimental part, p. 16440 - 16443 (2011/12/13)
A palladium-catalyzed desymmetrization of alkyne-tethered silacyclobutanes to give silacycles possessing a tetraorganosilicon stereocenter has been developed, and high chemo- and enantioselectivities have been achieved by the use of a newly synthesized ch
Synthesis of unsymmetrical biaryls from arylsilacyclobutanes
Denmark, Scott E.,Wu, Zhicai
, p. 1495 - 1498 (2008/02/09)
(formula presented) Aryl(fluoro)silacyclobutanes and aryl(chloro)silacyclobutanes have been found to undergo cross-coupling reactions with aryl iodides. The rate of reaction and extent of homocoupling were dramatically affected by the addition of ligands for the palladium catalyst. With (t-Bu)3P a wide range of electronically and structurally diverse unsymmetrical biaryls have been prepared in good to excellent yields.
