Technology Process of 1,6-diaminoperylene bisimide
There total 3 articles about 1,6-diaminoperylene bisimide which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide;
With
ammonium cerium (IV) nitrate; nitric acid;
In
dichloromethane;
at 25 ℃;
for 48h;
Inert atmosphere;
With
tin(II) chloride dihdyrate;
In
tetrahydrofuran;
at 25 - 80 ℃;
for 2.33333h;
Overall yield = 82 %;
Inert atmosphere;
Reflux;
DOI:10.3390/molecules19010327
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 4-methyl-morpholine / acetic acid
2.1: ammonium cerium (IV) nitrate; nitric acid / dichloromethane / 48 h / 25 °C / Inert atmosphere
2.2: 2.33 h / 25 - 80 °C / Inert atmosphere; Reflux
With
4-methyl-morpholine; ammonium cerium (IV) nitrate; nitric acid;
In
dichloromethane; acetic acid;
DOI:10.3390/molecules19010327
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: 4-methyl-morpholine / acetic acid
2.1: ammonium cerium (IV) nitrate; nitric acid / dichloromethane / 48 h / 25 °C / Inert atmosphere
2.2: 2.33 h / 25 - 80 °C / Inert atmosphere; Reflux
With
4-methyl-morpholine; ammonium cerium (IV) nitrate; nitric acid;
In
dichloromethane; acetic acid;
DOI:10.3390/molecules19010327
