1,7-diaminoperylene bisimide

Base Information

• Chemical Name: 1,7-diaminoperylene bisimide
• CAS No.: 1415680-20-4
• Molecular Formula: C₃₆H₃₂N₄O₄
• Molecular Weight: 584.674
• Mol file: 1415680-20-4.mol

Synonyms:1,7-diaminoperylene bisimide

Chemical Property of 1,7-diaminoperylene bisimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,7-diaminoperylene bisimide

There total 7 articles about 1,7-diaminoperylene bisimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone (1257079-47-2) → 1,7-diaminoperylene bisimide (1415680-20-4)

Guidance literature:

With tin(II) chloride dihdyrate; In tetrahydrofuran; at 25 - 80 ℃; for 6.3h; Inert atmosphere;

DOI:10.1016/j.dyepig.2012.09.003

Reference yield:

N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide (41572-86-5) → 1,7-diaminoperylene bisimide (1415680-20-4) + 1,6-diaminoperylene bisimide (1537195-43-9)

Guidance literature:

N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide; With ammonium cerium (IV) nitrate; nitric acid; In dichloromethane; at 25 ℃; for 48h; Inert atmosphere;

With tin(II) chloride dihdyrate; In tetrahydrofuran; at 25 - 80 ℃; for 2.33333h; Overall yield = 82 %; Inert atmosphere; Reflux;

DOI:10.3390/molecules19010327

Reference yield:

N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide (41572-86-5) → 1,7-diaminoperylene bisimide (1415680-20-4)

Guidance literature:

Multi-step reaction with 2 steps

1: ammonium cerium (IV) nitrate; nitric acid / dichloromethane / 48 h / 25 °C / Inert atmosphere

2: tin(II) chloride dihdyrate / tetrahydrofuran / 6.3 h / 25 - 80 °C / Inert atmosphere

With ammonium cerium (IV) nitrate; tin(II) chloride dihdyrate; nitric acid; In tetrahydrofuran; dichloromethane;

DOI:10.1016/j.dyepig.2012.09.003

upstream raw materials:

N,N'-bis(cyclohexyl)perylene-3,4,9,10-tetracarboxylic acid diimide

2,9-dicyclohexyl-5,12-dinitroanthra[2,1,9-def:6,5,10-d′e′f′]-diisoquinoline-1,3,8,10(2H,9H)-tetraone

cyclohexylamine

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride