((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh⁽¹⁺⁾*BF₄^(1-)=(((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh)BF₄

Base Information

Chemical Name:((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh⁽¹⁺⁾*BF₄^(1-)=(((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh)BF₄
CAS No.:919992-29-3
Molecular Formula:BF₄*C₄₆H₅₀P₂RhS₂
Molecular Weight:918.693
Hs Code.:

((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>CH<sub>2</sub>SC<sub>6</sub>H<sub>2</sub>(CH<sub>3</sub>)3)2Rh<sup>(1+)</sup>*BF<sub>4</sub><sup>(1-)</sup>=(((C<sub>6</sub>H<sub>5</sub>)2PCH<sub>2</sub>CH<sub>2</sub>SC<sub>6</sub>H<sub>2</sub>(CH<sub>3</sub>)3)2Rh)BF<sub>4</sub>

Synonyms:((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh⁽¹⁺⁾*BF₄^(1-)=(((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh)BF₄

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Chemical Property of ((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh⁽¹⁺⁾*BF₄^(1-)=(((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh)BF₄

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Technology Process of ((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh⁽¹⁺⁾*BF₄^(1-)=(((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh)BF₄

There total 1 articles about ((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh⁽¹⁺⁾*BF₄^(1-)=(((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh)BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 14104-20-2
silver tetrafluoroborate

: di-μ-chlorobis(norbornadiene)dirhodium(I)

: 919992-40-8
(2-(mesitylthio)ethyl)diphenylphosphine

: 919992-29-3
((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh⁽¹⁺⁾*BF₄^(1-)=(((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh)BF₄

Guidance literature:: In dichloromethane; under N2; soln. of Rh complex and AgBF4 in CH2Cl2 stirred for 1 h; filtered dropwise through Celite; filtrate dilited with CH2Cl2; soln. of ligand in CH2Cl2 added dropwise over 5 min at room temp.; stirred for 3 h; solvent removed; recrystd. from CH2Cl2-pentane;
DOI:10.1021/ja0661010

Reference yield:

: 919992-29-3
((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh⁽¹⁺⁾*BF₄^(1-)=(((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2Rh)BF₄

: 201230-82-2
carbon monoxide

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 919992-39-5
((C₆H₅)2PCH₂CH₂SC₆H₂(CH₃)3)2RhCl(CO)

Guidance literature:: In dichloromethane-d2; in air-free NMR tube; Rh complex dissolved in CD2Cl2; solid (Ph3P)2NCl (1 equiv.) added; CO (1 atm) introduced; 30 s; not isolated; detd. by (1)H and (31)P NMR spectra;
DOI:10.1021/ja0661010