(tert-butylimino)(trichloro)vanadium

Base Information

Chemical Name:(tert-butylimino)(trichloro)vanadium
CAS No.:80545-62-6
Molecular Formula:C4H9Cl3NV
Molecular Weight:228.423
Hs Code.:

Synonyms:

Suppliers and Price of (tert-butylimino)(trichloro)vanadium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 6 raw suppliers

Chemical Property of (tert-butylimino)(trichloro)vanadium

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (tert-butylimino)(trichloro)vanadium

There total 8 articles about (tert-butylimino)(trichloro)vanadium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 38662-39-4
t-butyl-N-sulfinylamine

: 7727-18-6
vanadium(V) oxychloride

: 80545-62-6
tert-butylimidovanadium(V) trichloride

Guidance literature:: In hexane; byproducts: SO2; Sonication; (Ar) VOCl3 in hexane at room temp. was added to soiln. t-BuNSO in hexane, refluxed for 2 h; volatiles were removed in vacuo at 20°C, residue was suspnd. in pentane by sonication and kept at -80°C for 24 h, ppt. was decanted, washed with chilled pentane and dried in vacuo;
DOI:10.1039/c0dt01133a

Reference yield: 85.0%

: 7727-18-6
vanadium(V) oxychloride

: 75-64-9
tert-butylamine

: 2{NH₃C(CH₃)3}⁽¹⁺⁾*{(VOCl₃)O(VOCl₃)}^(2-)={NH₃C(CH₃)3}2{(VOCl₃)O(VOCl₃)}

: 80545-62-6
tert-butylimidovanadium(V) trichloride

Guidance literature:: In pentane; byproducts: H2O; under Ar; slow addn. of amine soln. to dissolved VOCl3 under stirring at -78°C; stirred for 30 min; removing of ice bath; further stirring until reaction mixture was warmed up to 25°C; filtration of (NH3-t-bu-(VOCl3)2O); washed (CH2Cl2 and n-pentane); dried under vac.; solvent removed from mother liquor under vacuo; sublimation of residue (80°C, high vac.); elem. anal.; NMR; IR;

Reference yield: 68.0%

: 7727-18-6
vanadium(V) oxychloride

: 70024-35-0
(t-butylimido)tris(trimethylsiloxy)vanadium(V)

: 80545-62-6
tert-butylimidovanadium(V) trichloride

Guidance literature:: In hexane; under N2; VOCl3 is added dropwise to a soln. of the starting complex inhexane at 0°C with stirring, cooled to -80°C, allowed to stand for 1 h; the solvent is decanted, the residue is washed, recrystd., elem. anal.;