cis,cis,trans-hydrido((PhCH₂)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Base Information

• Chemical Name: cis,cis,trans-hydrido((PhCH₂)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)
• CAS No.: 107031-79-8
• Molecular Formula: C₄₅H₃₈O₂P₂RuS
• Molecular Weight: 805.879

Synonyms:cis,cis,trans-hydrido((PhCH₂)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Chemical Property of cis,cis,trans-hydrido((PhCH₂)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

Chemical Property:

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Technology Process of cis,cis,trans-hydrido((PhCH₂)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

There total 2 articles about cis,cis,trans-hydrido((PhCH₂)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{ruthenium(0) dicarbonyltris(triphenylphosphine)} (35880-54-7,61647-76-5,184490-77-5,65635-71-4) + phenylmethanethiol (100-53-8) → cis,cis,trans-hydrido((PhCH2)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (107031-79-8)

Guidance literature:

In tetrahydrofuran; byproducts: PPh3; under N2 or Ar, react. in soln. at room temp. for 3 h; concn. by vac. distn., addn. of hexane, filtn. of ppt.;

Reference yield:

dibenzyl disulphide (150-60-7) + cis-RuH2(CO)2(PPh3)2 (239076-83-6,20574-17-8,21029-29-8) → cis,cis,trans-hydrido((PhCH2)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (107031-79-8)

Guidance literature:

In tetrahydrofuran; byproducts: H2, PhCH2SH; at room temp.;

DOI:10.1016/S0020-1693(00)87726-9

Reference yield:

cis,cis,trans-hydrido((PhCH2)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II) (107031-79-8) + carbon monoxide (201230-82-2) → tricarbonylbis(triphenylphosphine)ruthenium(0) (20332-49-4,14741-36-7)

Guidance literature:

In tetrahydrofuran; byproducts: PhCH2SH; 1 atm CO or 6 Torr CO in Ar; not isolated, reaction followed by UV/VIS and (31)P-NMR spectroscopy; Kinetics;

upstream raw materials:

dibenzyl disulphide

cis-RuH₂(CO)2(PPh₃)2

{ruthenium⁽⁰⁾ dicarbonyltris(triphenylphosphine)}

phenylmethanethiol

Downstream raw materials:

tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾

cis,cis,trans-hydrido(Cl)(carbonyl)2(triphenylphosphine)2ruthenium(II)

cis,cis,trans-hydrido((Ph)thiolato)(carbonyl)2(triphenylphosphine)2ruthenium(II)

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