(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl)

Base Information

Chemical Name:(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl)
CAS No.:355840-50-5
Molecular Formula:C₂₇H₁₉ClF₁₂N₂Pt
Molecular Weight:829.975
Hs Code.:

(3,5-(CF<sub>3</sub>)2C<sub>6</sub>H<sub>3</sub>-N=CMe-CMe=N-3,5-(CF<sub>3</sub>)2C<sub>6</sub>H<sub>3</sub>)Pt(o-Tol)(Cl)

Synonyms:(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl)

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Chemical Property of (3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl)

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Technology Process of (3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl)

There total 1 articles about (3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 355840-60-7
cis-[(o-MeC₆H₄)2Pt(SMe₂)2]

: 400608-66-4
N,N’-bis-(3,5di(trifluoromethyl)phenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene

: trans-Pt(Cl)(o-Tol)(SMe₂)2

: 355840-50-5
(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl)

Guidance literature:: In diethyl ether; dichloromethane; toluene; soln. HCl in Et2O was added to soln. cis-Pt(o-Tol)2(SMe2)2 in CH2Cl2 andstirred for 1 h, solvent was removed, residue was washed with cold Et2O , soln. diimine ligand in toluene was added and stirred at 70°C for 14 h; solvent was removed, residue was chromed. (silica/CH2Cl2), product was washed with pentane and dried in vacuo; elem. anal.;
DOI:10.1021/ja010277e

Reference yield: 74.0%

: 355840-50-5
(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(Cl)

: 2923-28-6
silver trifluoromethanesulfonate

: 75-05-8,26809-02-9
acetonitrile

: 355840-55-0
(3,5-(CF₃)2C₆H₃-N=CMe-CMe=N-3,5-(CF₃)2C₆H₃)Pt(o-Tol)(NCMe)OTf

Guidance literature:: In tetrahydrofuran; acetonitrile; AgOTf was added to soln. monochloro complex in THF-MeCN and stirred for 20 min; mixt. was filtered, solvent was removed, residue was dissolved in Et2O, pentane was added and soln. was cooled to -20°C; elem. anal.;
DOI:10.1021/ja010277e