bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

Base Information

Chemical Name:bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)
CAS No.:80939-30-6
Molecular Formula:C₁₂H₁₀Cl₂Fe₄S₆*2C₂₄H₂₀P
Molecular Weight:1319.69
Hs Code.:

Synonyms:bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

Suppliers and Price of bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

There total 7 articles about bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 80765-11-3
bis(tetraphenylphosphonium) hexakis(μ-thiophenolato)-tetrachlorotetraferrate(II)

: 6493-73-8
dibenzyltrisulfide

: 80939-30-6
bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

Guidance literature:: In acetonitrile; soln. of dibenzyltrisufide was added to soln. of complex (mol ratio 4:1) (N2); stirring for 20 min; addn. of EtOH/Et2O, standing for ca 2 h; elem. anal.;
DOI:10.1021/ja00371a016

Reference yield: 66.0%

: 84032-42-8
2P(C₆H₅)4⁽¹⁺⁾*{Fe₂S₂(SC₆H₅)4}^(2-) = {P(C₆H₅)4}2{Fe₂S₂(SC₆H₅)4}

: iron(II) chloride

: 80939-30-6
bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

Guidance literature:: In N,N-dimethyl-formamide; FeCl2 was suspended in a soln. of Fe complex in DMF, stirring for 20 min, filtration, addn. of Et2O, standing for ca. 2 h; drying in vac.;
DOI:10.1021/ja00328a033

Reference yield: 53.0%

: bis(tetraphenylphosphonium) tetrachlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

: 2P(C₆H₅)4⁽¹⁺⁾*Fe₄S₄(SC₆H₅)4^(2-)=[P(C₆H₅)4]2[Fe₄S₄(SC₆H₅)4]

: 80939-30-6
bis(tetraphenylphosphonium) bis(thiophenolato)dichlorotetrakis(μ3-sulfido)tetraferrate(2II,2III)

Guidance literature:: In N,N-dimethyl-formamide; educts mixing (N2); filtration after 5 min; standing at room temp. for ca 12 h; addn. of Et2O, standing for 5 h;
DOI:10.1021/ja00371a016