tris(2,6-diisopropylphenylimido)rhenium chloride

Base Information

Chemical Name:tris(2,6-diisopropylphenylimido)rhenium chloride
CAS No.:135228-54-5
Molecular Formula:C₃₆H₅₁ClN₃Re
Molecular Weight:747.481
Hs Code.:

Synonyms:tris(2,6-diisopropylphenylimido)rhenium chloride

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Chemical Property of tris(2,6-diisopropylphenylimido)rhenium chloride

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Technology Process of tris(2,6-diisopropylphenylimido)rhenium chloride

There total 4 articles about tris(2,6-diisopropylphenylimido)rhenium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 75-77-4
chloro-trimethyl-silane

: 24544-04-5
2,6-diisopropylbenzenamine

: rhenium(VII) oxide

: 135228-54-5
tris(2,6-diisopropylphenylimido)rhenium chloride

Guidance literature:: With N(C₂H₅)3; In dichloromethane; byproducts: ((CH3)3Si)2O, {HN(C2H5)3}Cl; addn. of 155 mmol of 2,6-diisopropylaniline, 361 mmol of NEt3 and (slowly) 413 mmol of Me3SiCl to a soln. of 25.8 mmol of Re2O7 in 200 ml CH2Cl2 at -40°C, warming to 25°C, stirring under N2 for 3 days and evaporation;; extraction with ether, filtration, evaporation and washing with cold pentane; detn. by elem. anal. and (1)H-NMR spectroscopy;;
DOI:10.1021/om00028a032

Reference yield:

: 135228-51-2
HRe{NC₆H₃(CH(CH₃)2)2}3

: 135228-54-5
tris(2,6-diisopropylphenylimido)rhenium chloride

Guidance literature:: With CCl₄; In not given; byproducts: CHCl3; addn. of CCl4 to Re-complex; not isolated, detected by NMR-spect.;

Reference yield:

: N(C₂H₅)4⁽¹⁺⁾*Re{NC₆H₃(CH(CH₃)2)2}3^(1-)={N(C₂H₅)4}{Re(NC₆H₃(CH(CH₃)2)2)3}

: 135228-54-5
tris(2,6-diisopropylphenylimido)rhenium chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 2,6-di-tert-butylpyridinium triflate / not given

2: CCl₄ / not given

With 2,6-di-tert-butylpyridinium triflate; CCl₄; In not given;