(2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

Base Information

Chemical Name:(2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate
CAS No.:130082-72-3
Molecular Formula:C₃₂H₄₄O₃S
Molecular Weight:508.766
Hs Code.:

(2E/Z,3aα,7aβ)-<Octahydro-2-(phenylmethylene)-3aH-inden-3a-yl>methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

Synonyms:(2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

Suppliers and Price of (2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

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Technology Process of (2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

There total 10 articles about (2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 6553-96-4
2,4,6-triisopropylphenylsulfonyl chloride

: 130082-69-8
(3aα,7aβ)-Octahydro-2-(phenylmethylene)-3aH-indene-3a-methanol

: 130082-72-3
(2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

Guidance literature:: With sodium hydride; at 80 ℃;
DOI:10.1039/c39900000972

Reference yield:

: (1S,2S)-1-(3-Phenyl-prop-2-ynyl)-2-phenylselanylmethyl-cyclohexanecarboxylic acid

: 130082-72-3
(2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

Guidance literature:: Multi-step reaction with 4 steps

1: diethyl ether

2: 96 percent / Ph₃SnH, AIBN / benzene / Heating

3: LiAlH₄ / tetrahydrofuran / 5 h

4: 81 percent / pyridine / 80 °C

With pyridine; lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); triphenylstannane; In tetrahydrofuran; diethyl ether; benzene;
DOI:10.1021/jo00076a057

Reference yield:

: 130082-81-4
cis-Hexahydro-7a-(3-phenyl-2-propynyl)-1(3H)-isobenzofuranone

: 130082-72-3
(2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate

Guidance literature:: Multi-step reaction with 5 steps

1: NaH / 1.) THF, reflux, 50 min, 2.) THF, HMPA, reflux, 4 h

2: diethyl ether

3: 96 percent / Ph₃SnH, AIBN / benzene / Heating

4: LiAlH₄ / tetrahydrofuran / 5 h

5: 81 percent / pyridine / 80 °C

With pyridine; lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); triphenylstannane; sodium hydride; In tetrahydrofuran; diethyl ether; benzene;
DOI:10.1021/jo00076a057