Technology Process of 10-(2-bromophenyl)-10H-dibenzo[b,e]iodininium iodide
There total 6 articles about 10-(2-bromophenyl)-10H-dibenzo[b,e]iodininium iodide which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
1-bromo-2-((2-iodophenyl)(phenyl)methyl)benzene;
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 ℃;
for 0.333333h;
Inert atmosphere;
With
trifluorormethanesulfonic acid;
In
dichloromethane;
at 20 ℃;
for 1.08333h;
Inert atmosphere;
With
potassium iodide;
In
diethyl ether; water;
for 0.0833333h;
DOI:10.1021/ja4114962
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.33 h / 0 °C / Inert atmosphere
1.2: 255 / 1.42 h / 20 °C / Inert atmosphere
1.3: 0.08 h / Inert atmosphere
2.1: tetrabutylammomium bromide; copper(I) bromide / acetonitrile / 120 h / Reflux; Inert atmosphere
3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.33 h / 0 °C / Inert atmosphere
3.2: 255 / 1.08 h / 20 °C / Inert atmosphere
3.3: 0.08 h
With
tetrabutylammomium bromide; 3-chloro-benzenecarboperoxoic acid; copper(I) bromide;
In
dichloromethane; acetonitrile;
DOI:10.1021/ja4114962
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: tetrabutylammomium bromide; copper(I) bromide / acetonitrile / 120 h / Reflux; Inert atmosphere
2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.33 h / 0 °C / Inert atmosphere
2.2: 255 / 1.08 h / 20 °C / Inert atmosphere
2.3: 0.08 h
With
tetrabutylammomium bromide; 3-chloro-benzenecarboperoxoic acid; copper(I) bromide;
In
dichloromethane; acetonitrile;
DOI:10.1021/ja4114962
