Technology Process of 10-phenyl-10H-dibenzo[b,e]iodininium bromide
There total 1 articles about 10-phenyl-10H-dibenzo[b,e]iodininium bromide which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
((2-iodophenyl)methylene)dibenzene 2-benzhydrylaniline;
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 ℃;
for 0.333333h;
Inert atmosphere;
With
trifluorormethanesulfonic acid;
In
dichloromethane;
at 20 ℃;
for 1.42h;
Inert atmosphere;
With
sodium bromide;
In
diethyl ether; water;
for 0.0833333h;
Inert atmosphere;
DOI:10.1021/ja4114962
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: tetrabutylammomium bromide; copper(I) bromide / acetonitrile / 120 h / Reflux; Inert atmosphere
2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.33 h / 0 °C / Inert atmosphere
2.2: 255 / 1.08 h / 20 °C / Inert atmosphere
2.3: 0.08 h
3.1: 0.25 h / 200 °C / Schlenk technique; Inert atmosphere
With
tetrabutylammomium bromide; 3-chloro-benzenecarboperoxoic acid; copper(I) bromide;
In
dichloromethane; acetonitrile;
DOI:10.1021/ja4114962
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: tetrabutylammomium bromide; copper(I) bromide / acetonitrile / 120 h / Reflux; Inert atmosphere
2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.33 h / 0 °C / Inert atmosphere
2.2: 255 / 1.08 h / 20 °C / Inert atmosphere
2.3: 0.08 h
3.1: 0.25 h / 200 °C / Schlenk technique; Inert atmosphere
4.1: tert.-butyl lithium / diethyl ether / 3.16 h / -78 °C / Inert atmosphere
4.2: 20 °C / Inert atmosphere
With
tetrabutylammomium bromide; tert.-butyl lithium; 3-chloro-benzenecarboperoxoic acid; copper(I) bromide;
In
diethyl ether; dichloromethane; acetonitrile;
DOI:10.1021/ja4114962
