[4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

Base Information

Chemical Name:[4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester
CAS No.:330596-40-2
Molecular Formula:C₅₁H₅₃NO₁₅Si
Molecular Weight:948.065
Hs Code.:

[4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

Synonyms:[4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

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Chemical Property of [4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

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Technology Process of [4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

There total 4 articles about [4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 28920-43-6
(fluorenylmethoxy)carbonyl chloride

: 330596-39-9
[4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-hydroxy-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

: 330596-40-2
[4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: With pyridine; at 20 ℃;
DOI:10.1021/ol007062e

Reference yield:

: 302783-17-1
methyl 2,3-di-O-acetyl-4,6-O-p-methoxybenzylidene-α-D-glucopyranoside

: 330596-40-2
[4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / Bu₂BOTf; BH₃*THF / CH₂Cl₂ / 0 °C

2: 77 percent / DCC; DMAP / CH₂Cl₂ / 20 °C

3: 97 percent / DDQ / CH₂Cl₂; H₂O / 20 °C

4: 70 percent / pyridine / 20 °C

With pyridine; dmap; borane-THF; di-n-butylboryl trifluoromethanesulfonate; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1021/ol007062e

Reference yield:

: 330596-36-6
methyl 2,3-di-O-acetyl-4-O-p-methoxybenzyl-α-D-glucopyranoside

: 330596-40-2
[4-(tert-Butyl-diphenyl-silanyloxymethyl)-2-nitro-phenoxy]-acetic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-3-(9H-fluoren-9-ylmethoxycarbonyloxy)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 77 percent / DCC; DMAP / CH₂Cl₂ / 20 °C

2: 97 percent / DDQ / CH₂Cl₂; H₂O / 20 °C

3: 70 percent / pyridine / 20 °C

With pyridine; dmap; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1021/ol007062e