1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate

Base Information

Chemical Name:1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate
CAS No.:114371-50-5
Molecular Formula:C₁₆H₂₉NO₃
Molecular Weight:283.411
Hs Code.:

1,1-dimethylethyl <S-(E)>-<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate

Synonyms:1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate

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Chemical Property of 1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate

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Technology Process of 1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate

There total 3 articles about 1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 114371-49-2
ethyl -5-cyclohexyl-4-<<(1,1-dimethylethoxy)carbonyl>amino>-2-pentenoate

: 114371-50-5
1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate

Guidance literature:: ethyl -5-cyclohexyl-4-<<(1,1-dimethylethoxy)carbonyl>amino>-2-pentenoate; With boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; for 0.25h;

With diisobutylaluminium hydride; In hexane; dichloromethane; at -78 ℃; for 2h;
DOI:10.1021/jo991065r

Reference yield:

: 98105-42-1
(S)-2-(t-butoxycarbonylamino)-3-cyclohexyl-1-propanal

: 114371-50-5
1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: benzene / 0.5 h / 30 °C

2.1: BF₃*Et₂O / CH₂Cl₂ / 0.25 h / -78 °C

2.2: 86 percent / diisobutylaluminum hydride / CH₂Cl₂; hexane / 2 h / -78 °C

With boron trifluoride diethyl etherate; In dichloromethane; benzene; 1.1: olefination; Wittig reaction / 2.1: Reduction / 2.2: Reduction;
DOI:10.1021/jo991065r

Reference yield:

: 103322-56-1
tert-butyl [(1S)-2-cyclohexyl-1-(hydroxymethyl)ethyl]carbamate

: 114371-50-5
1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate

Guidance literature:: Multi-step reaction with 3 steps

1.1: Dess-Martin periodinane / CH₂Cl₂ / 2 h / 25 °C

2.1: benzene / 0.5 h / 30 °C

3.1: BF₃*Et₂O / CH₂Cl₂ / 0.25 h / -78 °C

3.2: 86 percent / diisobutylaluminum hydride / CH₂Cl₂; hexane / 2 h / -78 °C

With boron trifluoride diethyl etherate; Dess-Martin periodane; In dichloromethane; benzene; 1.1: Oxidation / 2.1: olefination; Wittig reaction / 3.1: Reduction / 3.2: Reduction;
DOI:10.1021/jo991065r