3-Phenylazoacetylacetone

Base Information

Chemical Name:3-Phenylazoacetylacetone
CAS No.:56276-49-4
Molecular Formula:C11H12 N2 O2
Molecular Weight:204.228
Hs Code.:2927000090
European Community (EC) Number:260-089-9
NSC Number:518715
UNII:4LP68P99TS
DSSTox Substance ID:DTXSID401306742
Nikkaji Number:J267.362B
Wikipedia:3-Phenylazoacetylacetone
Wikidata:Q4634187,Q106902726
Mol file:56276-49-4.mol

Synonyms:3-phenylazoacetylacetone;56276-49-4;3-(Phenylazo)-2,4-pentanedione;3-phenyldiazenylpentane-2,4-dione;2,4-Pentanedione, 3-(phenylazo)-;Phenyl-azo-acetylaceton;3-Phenylazo-2,4-pentanedione;3-Phenylazo-pentane-2,4-dione;3-(Phenylazo)pentane-2,4-dione;3-phenylazopentane-2,4-dione;Phenyl-azo-acetylaceton [German];EINECS 260-089-9;4LP68P99TS;NSC-518715;3-(phenyldiazenyl)pentane-2,4-dione;NSC518715;3-(2-phenyldiazen-1-yl)pentane-2,4-dione;UNII-4LP68P99TS;CBDivE_003814;SCHEMBL2479589;DTXSID401306742;MFCD00026233;AKOS005207224;AKOS025116722;NSC 518715;(e)-3-(phenyldiazenyl)pentane-2,4-dione;3-[(E)-phenyldiazenyl]-2,4-pentanedione;LS-101715;FT-0616336;3-(PHENYLHYDRAZONO)-2,4-PENTANEDIONE;3-(2-PHENYLDIAZENYL)-2,4-PENTANEDIONE;2,4-PENTANEDIONE, 3-(2-PHENYLDIAZENYL)-;A929374;SR-01000311165;Q4634187;SR-01000311165-1

Suppliers and Price of 3-Phenylazoacetylacetone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3-(2-Phenyldiazen-1-yl)pentane-2,4-dione
500mg
$ 110.00

Matrix Scientific
3-Phenylazo-pentane-2,4-dione
1g
$ 378.00

American Custom Chemicals Corporation
3-PHENYLAZO-2,4-PENTANEDIONE 95.00%
500MG
$ 796.95

Alfa Aesar
3-Phenylazo-2,4-pentanedione, 98%
5g
$ 8.77

AK Scientific
3-Phenylazo-pentane-2,4-dione
1g
$ 560.00

AHH
3-Phenylazoacetylacetone 98%
500g
$ 568.00

Total 15 raw suppliers

Chemical Property of 3-Phenylazoacetylacetone

Chemical Property:

Vapor Pressure:0.00735mmHg at 25°C
Melting Point:86-87°C
Boiling Point:269.2°Cat760mmHg
PKA:7.01±0.59(Predicted)
Flash Point:107.9°C
PSA：58.86000
Density:1.11g/cm³
LogP:2.31690
XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:204.089877630
Heavy Atom Count:15
Complexity:254

Purity/Quality:

99%, ^*data from raw suppliers

3-(2-Phenyldiazen-1-yl)pentane-2,4-dione ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 22-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)C(C(=O)C)N=NC1=CC=CC=C1

Technology Process of 3-Phenylazoacetylacetone

There total 3 articles about 3-Phenylazoacetylacetone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 62-53-3
aniline

: 123-54-6,81235-32-7
acetylacetone

: 56276-49-4
3-phenylazo-pentane-2,4-dione

Guidance literature:: aniline; With hydrogenchloride; sodium nitrite; In water; at 0 - 5 ℃; for 0.5h;

acetylacetone; With ammonium acetate; In ethanol; water; at 0 - 5 ℃; pH=5 - 6;

Reference yield: 70.0%

: 100-63-0
phenylhydrazine

: 123-54-6,81235-32-7
acetylacetone

: 56276-49-4
3-phenylazo-pentane-2,4-dione

Guidance literature:: phenylhydrazine; With copper(ll) sulfate pentahydrate; potassium carbonate; p-toluenesulfonyl chloride; In dichloromethane; at 20 ℃; for 2h;

acetylacetone;
DOI:10.1039/c5nj01760b