[AuCl(sodium triphenylphosphane monosulfonate)]

Base Information

• Chemical Name: [AuCl(sodium triphenylphosphane monosulfonate)]
• CAS No.: 569674-13-1
• Molecular Formula: C₁₈H₁₄AuClO₃PS*Na
• Molecular Weight: 596.756
• Mol file: 569674-13-1.mol

Synonyms:[AuCl(sodium triphenylphosphane monosulfonate)]

Chemical Property of [AuCl(sodium triphenylphosphane monosulfonate)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of [AuCl(sodium triphenylphosphane monosulfonate)]

There total 1 articles about [AuCl(sodium triphenylphosphane monosulfonate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + sodium 3-(diphenylphosphanyl)benzenesulfonate (63995-75-5) → [AuCl(sodium triphenylphosphane monosulfonate)] (569674-13-1)

Guidance literature:

In acetone; under N2; 1 equiv. of Na-salt in Me2CO added to Me2CO soln. of Au-complex, stirring for 2 h; filtered, filtrate evapd. under vac., residue recrystd. from MeOH;

DOI:10.1002/ejic.200390186

Reference yield: 80.0%

[AuCl(sodium triphenylphosphane monosulfonate)] (569674-13-1) + guanidine hydrochloride (50-01-1) → (guanidinium)[AuCl(Ph2P(C6H4-m-SO3))] (569674-08-4)

Guidance literature:

In methanol; under N2; equimolar amts.; slow evapn. over one week;

DOI:10.1002/ejic.200390186

Reference yield: 69.0%

[AuCl(sodium triphenylphosphane monosulfonate)] (569674-13-1) + 2-sulfanyl-1,3-benzoxazole (2382-96-9,118090-08-7) → [Au(Sbenzoxazole)(sodium triphenylphosphane monosulfonate)] (1338814-11-1)

Guidance literature:

With KOH; In methanol; Au complex added to soln. of KOH in MeOH contg. thiol; stirred at room temp. for ca. 20 h; evapd. to dryness under vac.; extd. in CH2Cl2; combined extracts passed through Celite; concd. under vac.; pentane or Et2O added; filtered; ppt.dried in air; elem. anal.;

DOI:10.1039/c1dt10892a

upstream raw materials:

(tetrahydrothiophene)gold(I) chloride

sodium 3-(diphenylphosphanyl)benzenesulfonate

Downstream raw materials:

(guanidinium)[AuCl(Ph₂P(C₆H₄-m-SO₃))]

[Au(SC₄HN₂Me₂)(sodium triphenylphosphane monosulfonate)]

[Au(Sbenzoxazole)(sodium triphenylphosphane monosulfonate)]

[Au(SC₄H₃N₂)(sodium triphenylphosphane monosulfonate)]