1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol

Base Information

• Chemical Name: 1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol
• CAS No.: 172467-95-7
• Molecular Formula: C₂₃H₃₇ClO₂S
• Molecular Weight: 413.065
• Mol file: 172467-95-7.mol

Synonyms:1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol

Chemical Property of 1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol

There total 1 articles about 1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

cyclopentadecanone (502-72-7) + chloromethyl p-tolyl sulfoxide (24824-93-9) → 1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol (172467-95-7)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃;

DOI:10.1016/0040-4039(95)01435-K

Reference yield: 97.0%

1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol (172467-95-7) → 3'-(p-tolylsulfinyl)spiro[cyclopentadecane-1,2'-oxirane] (851662-61-8)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; tert-butyl alcohol; at 0 ℃; for 0.166667h;

DOI:10.1016/j.tet.2006.06.112

Reference yield: 94.0%

acetic anhydride (108-24-7) + 1-[Chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecanol (172467-95-7) → Acetic acid 1-[chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecyl ester (172467-96-8)

Guidance literature:

With pyridine; dmap;

DOI:10.1016/0040-4039(95)01435-K

upstream raw materials:

cyclopentadecanone

chloromethyl p-tolyl sulfoxide

Downstream raw materials:

Acetic acid 1-[chloro-(toluene-4-sulfinyl)-methyl]-cyclopentadecyl ester

3'-(p-tolylsulfinyl)spiro[cyclopentadecane-1,2'-oxirane]

1-(benzylamino)cyclopentadecanecarbaldehyde

methyl 1-(benzylamino)cyclopentadecanecarboxylate