Hexamminecobalt(III) tricarbonatocobaltate(III)

Base Information

Chemical Name:Hexamminecobalt(III) tricarbonatocobaltate(III)
CAS No.:15279-18-2
Molecular Formula:C₃CoO₉*CoH₁₈N₆
Molecular Weight:400.197
Hs Code.:
DSSTox Substance ID:DTXSID10165119
Mol file:15279-18-2.mol

Synonyms:HCTC;hexamminecobalt(III) tricarbonatocobaltate(III)

Suppliers and Price of Hexamminecobalt(III) tricarbonatocobaltate(III)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Hexamminecobalt(III) tricarbonatocobaltate(III)

Chemical Property:

Vapor Pressure:2.58E-05mmHg at 25°C
Boiling Point:333.6°Cat760mmHg
Flash Point:169.8°C
PSA：209.01000
Density:g/cm³
LogP:-5.39760
Hydrogen Bond Donor Count:6
Hydrogen Bond Acceptor Count:15
Rotatable Bond Count:0
Exact Mass:399.979913
Heavy Atom Count:20
Complexity:18.8

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C(=O)([O-])[O-].C(=O)([O-])[O-].C(=O)([O-])[O-].N.N.N.N.N.N.[Co+3].[Co+3]

Technology Process of Hexamminecobalt(III) tricarbonatocobaltate(III)

There total 2 articles about Hexamminecobalt(III) tricarbonatocobaltate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

: cobalt(II) nitrate hexahydrate

: 10534-89-1
hexammine cobalt(III) chloride

: 144-55-8
sodium hydrogencarbonate

: 15279-18-2,26176-52-3
[Co(NH₃)6]⁽³⁺⁾*[Co(CO₃)3]^(3-)=[Co(NH₃)6][Co(CO₃)3]

Guidance literature:: With dihydrogen peroxide; In water; aq. soln. of H2O2 was added with stirring to mixt. of Co(NO3)2*6H2O and NaHCO3 in water during 1 h; soln. was dild. to 1 l with water and stirred overnight; soln. of Co-NH3 complex in water was added; soln. was stirred and stored in ice bath for 24 h; filtered; washed (H2O); dried by drawing air; elem. anal.;
DOI:10.1016/S0020-1693(02)01236-7

Reference yield:

: 10534-89-1
hexammine cobalt(III) chloride

: 144-55-8
sodium hydrogencarbonate

: 7646-79-9,14543-09-0,16413-89-1
cobalt(II) chloride

: 15279-18-2,26176-52-3
[Co(NH₃)6]⁽³⁺⁾*[Co(CO₃)3]^(3-)=[Co(NH₃)6][Co(CO₃)3]

Guidance literature:: With dihydrogen peroxide; In water; to ice-cooled soln. of CoCl2 in NaHCO3 H2O2 added dropwise, Co(NH3)6Co(CO3)3 added; ppt. sepd., washed (ice-cold water), dried (dessicator);