Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer

Base Information

• Chemical Name: Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer
• CAS No.: 187387-17-3
• Molecular Formula: C₁₄₄H₁₅₂N₁₂Zn₃
• Molecular Weight: 2247.04

Synonyms:Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer

Chemical Property of Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer

Chemical Property:

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Technology Process of Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer

There total 5 articles about Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

[5,15-bis[3,5-di(tert-butyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) → Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer (187387-17-3) + μ-[10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) (187387-16-2) + [5,15-bis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) tetramer

Guidance literature:

With AgPF₆; In chloroform; acetonitrile; N2 atm.; 0.8 equiv of AgPF6, CH3CN/CHCl3 1:4, 25°C, 16 h;

DOI:10.1002/hlca.200590144

Reference yield: 25.0%

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (187387-14-0) + zinc diacetate (557-34-6) → Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer (187387-17-3) + μ-[10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) (187387-16-2) + [5,15-bis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) tetramer

Guidance literature:

With silver(I) hexafluorophosphate; In acetonitrile; stirring porphyrin with 0.5 equiv. AgPF6 (0.5 h, room temp., in dark), filtration, water addn., extn. into CHCl3, washing (water), drying (Na2SO4), Zn(OAc)2 addn., refluxing for 1 h; water addn., extn. into CHCl3, washing (water), drying (Na2SO4), repeated chromy. (Bio-Beads SX-1, C6H6);

DOI:10.1002/anie.199701351

Reference yield: 20.7%

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) (187387-14-0) → Zinc(II) 5,15-di(3,5-di-tert-butylphenyl)porphyrin meso-meso trimer (187387-17-3) + μ-[10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) (187387-16-2) + [5,15-bis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) tetramer

Guidance literature:

In benzonitrile; Electrolysis; 0.732 mF, 0.1 M NBu4ClO4 supporting electrolyte; GPC-HPLC;

DOI:10.1039/a707653c

upstream raw materials:

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

zinc diacetate

Downstream raw materials:

(Zn(C₄H₂NC(C₆H₃(C(CH₃)3)2)C₄NH₂CIC₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2(Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C)2)

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