tribromomethyl lithium

Base Information

• Chemical Name: tribromomethyl lithium
• CAS No.: 16644-71-6
• Molecular Formula: CBr₃Li
• Molecular Weight: 258.664
• Mol file: 16644-71-6.mol

Synonyms:tribromomethyl lithium

Chemical Property of tribromomethyl lithium

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of tribromomethyl lithium

There total 1 articles about tribromomethyl lithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon tetrabromide (558-13-4) + lithium (7439-93-2) → dibromocarbene (135226-15-2,4371-77-1) + tribromomethyl (4471-18-5) + tribromomethyl lithium (16644-71-6) + lithium bromide (7550-35-8)

Guidance literature:

In solid matrix; condensation of a stream of Li-atoms with CBr4 in an Ar-matrix at 15K on CsI (concn. Ar:CBr4 = 400-600, Li:CBr4 = 0.5-3);; determination by IR;;

DOI:10.1021/j100851a061

Reference yield: 62.0%

3-phenyl-propionaldehyde (104-53-0) + tribromomethyl lithium (16644-71-6) → 1,1,1-tribromo-4-phenylbutan-2-one

Guidance literature:

3-phenyl-propionaldehyde; tribromomethyl lithium;

With Dess-Martin periodane;

DOI:10.1246/cl.2004.98

upstream raw materials:

carbon tetrabromide

lithium