N-[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate

Base Information

Chemical Name:N-[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate
CAS No.:1207738-92-8
Molecular Formula:BF₄*C₄₂H₄₂FeN₂P
Molecular Weight:748.434
Hs Code.:

Synonyms:N-[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate

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Chemical Property of N-[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate

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Technology Process of N-[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate

There total 1 articles about N-[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1207738-87-1
N-[(1-diphenylthiophosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate

: 1207738-92-8
N-[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate

Guidance literature:: nickel; In acetonitrile; (Ar), Raney Ni washed with degassed CH3OH, Et2O, CH3CN, treated with soln. of Fe complex in CH3CN, stirred at room temp. for 24 h; filtered (celite), rinzed (CH3CN), concd., dried (vac.), elem. anal.;
DOI:10.1002/ejic.200801163

Reference yield: 84.0%

: 14104-20-2
silver tetrafluoroborate

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 1207738-92-8
N-[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazolium tetrafluoroborate

: N-[[(1-diphenylphosphanylferrocen-1'-yl)methyl]-N'-[(2,4,6-trimethylphenyl)methyl]-5,6-dimethylbenzimidazol-2-ylidene]rhodium(I)(cyclootadiene) tetrafluoroborate

Guidance literature:: With tBuOK; In tetrahydrofuran; dichloromethane; (Ar), tBuOK and Rh complex (2.1:1) degassed, treated with THF, stirred at room temp. for 30 min, slowly added to precoole to -78°C Fe complex (2 equiv.), stirred at -78°C for 15 min, at room temp. for 2h, evapd., took up into degassed CH2; filtered (celite), evapd.(vac.), chromy.(silica gel - CH2Cl2/acetone 95:5), elem. anal.;
DOI:10.1002/ejic.200801163