1-(tert-butyl)-6-methoxynaphthalene

Base Information

Chemical Name:1-(tert-butyl)-6-methoxynaphthalene
CAS No.:1263428-86-9
Molecular Formula:C₁₅H₁₈O
Molecular Weight:214.307
Hs Code.:

Synonyms:1-(tert-butyl)-6-methoxynaphthalene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(tert-butyl)-6-methoxynaphthalene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 1-(tert-butyl)-6-methoxynaphthalene

There total 1 articles about 1-(tert-butyl)-6-methoxynaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 83710-62-7
1-bromo-6-methoxynaphthalene

: 677-22-5
tert-butylmagnesium chloride

: 93-04-9
2-Methoxynaphthalene

: 1263428-86-9
1-(tert-butyl)-6-methoxynaphthalene

Guidance literature:: With 1.54H₂O*Cl₂Ni; 1,3-bis(cyclohexyl)imidazolium tetrafluoroborate; In tetrahydrofuran; at -10 ℃; for 1.5h; Inert atmosphere;
DOI:10.1021/ja202769t

Reference yield:

: 1263428-86-9
1-(tert-butyl)-6-methoxynaphthalene

: 1322595-16-3
C₃₆H₃₉Br

Guidance literature:: Multi-step reaction with 4 steps

1: boron tribromide / dichloromethane / 0 - 20 °C / Inert atmosphere

2: pyridine / dichloromethane / 4 h / 20 °C / Inert atmosphere

3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 12 h / 80 °C / Inert atmosphere

4: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; water; toluene / 24 h / 80 °C / Inert atmosphere

With pyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; boron tribromide; potassium carbonate; In 1,4-dioxane; ethanol; dichloromethane; water; toluene;
DOI:10.1002/chem.201101057

Reference yield:

: 1263428-86-9
1-(tert-butyl)-6-methoxynaphthalene

: 1322595-19-6
C₃₆H₃₉Br

Guidance literature:: Multi-step reaction with 5 steps

1: boron tribromide / dichloromethane / 0 - 20 °C / Inert atmosphere

2: pyridine / dichloromethane / 4 h / 20 °C / Inert atmosphere

3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 12 h / 80 °C / Inert atmosphere

4: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / ethanol; water; toluene / 24 h / 80 °C / Inert atmosphere

5: platinum(II) chloride / toluene / 24.08 h / 25 - 90 °C / Inert atmosphere

With pyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; boron tribromide; potassium carbonate; platinum(II) chloride; In 1,4-dioxane; ethanol; dichloromethane; water; toluene;
DOI:10.1002/chem.201101057