Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine)

Base Information

• Chemical Name: Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine)
• CAS No.: 217813-25-7
• Molecular Formula: C₂₆H₂₃INPPd
• Molecular Weight: 613.774
• Mol file: 217813-25-7.mol

Synonyms:Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine)

Chemical Property of Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine)

There total 1 articles about Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

iodobenzene (591-50-4) + N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine (153358-06-6) + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine) (217813-25-7)

Guidance literature:

In tetrahydrofuran; byproducts: dibenzylideneacetone, Pd; N2 atmosphere, addn. of phosphanyl-amine ligand and PhI to soln. of Pd complex at 50°C, stirring (50°C, 45 min); concn., filtration, removement of solvent (reduced pressure), washing (Et2O), drying (vacuum); elem. anal.;

DOI:10.1002/(sici)1099-0682(199811)1998:11<1811::aid-ejic1811>3.0.co;2-r

Reference yield: 94.0%

Pd(phenyl)I(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine) (217813-25-7) + silver trifluoromethanesulfonate (2923-28-6) + triphenylphosphine (603-35-0) → [Pd(phenyl)(P(C6H5)3)(N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine)](CF3SO3)*0.5C6H6

Guidance literature:

In dichloromethane; acetone; byproducts: AgI; N2 atmosphere, addn. of acetone soln. of PPh3 and Ag(CF3SO3) to CH2Cl2 soln. of Pd complex at 0°C, 0°C (45 min); concn., filtration, evapn. of solvent (vacuum), dissolution (CH2Cl2), pptn. (Et2O), decantation of supernatant soln., dissolution (CH2Cl2), pptn. on addn. of C6H6 and Et2O with stirring, filtration, washing (C6H6 andEt2O), drying (vacuum); elem. anal.;

DOI:10.1002/(sici)1099-0682(199811)1998:11<1811::aid-ejic1811>3.0.co;2-r

upstream raw materials:

iodobenzene

N-[2-(diphenylphosphanyl)benzylidene]-N-methylamine

bis(dibenzylideneacetone)-palladium⁽⁰⁾