(5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane

Base Information

Chemical Name:(5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane
CAS No.:1417996-00-9
Molecular Formula:C₂₆H₃₈O₃Si
Molecular Weight:426.671
Hs Code.:

Synonyms:(5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane

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Chemical Property of (5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane

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Technology Process of (5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane

There total 7 articles about (5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1417995-99-3
(2R,4R)-4-(methoxymethoxy)-2-methylhept-6-en-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1417996-00-9
(5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane

Guidance literature:: With 1H-imidazole; In dichloromethane; at -20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1002/ejoc.201201119

Reference yield:

: 1417995-98-2
(R)-4-benzyl-3-[(2R,4R)-4-(methoxymethoxy)-2-methylhept-6-enoyl]oxazolidin-2-one

: 1417996-00-9
(5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane

Guidance literature:: Multi-step reaction with 2 steps

1: sodium tetrahydroborate / tetrahydrofuran; water / 1 h / 0 - 20 °C / Inert atmosphere

2: 1H-imidazole / dichloromethane / 0.5 h / -20 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; In tetrahydrofuran; dichloromethane; water;
DOI:10.1002/ejoc.201201119

Reference yield:

: 1417995-97-1
(R)-4-benzyl-3-[(S)-4-(methoxymethoxy)hept-6-enoyl]oxazolidin-2-one

: 1417996-00-9
(5R,7R)-5-allyl-7,11,11-trimethyl-10,10-diphenyl-2,4,9-trioxa-10-siladodecane

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

1.2: 3.5 h / -75 °C / Inert atmosphere

2.1: sodium tetrahydroborate / tetrahydrofuran; water / 1 h / 0 - 20 °C / Inert atmosphere

3.1: 1H-imidazole / dichloromethane / 0.5 h / -20 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; lithium hexamethyldisilazane; In tetrahydrofuran; dichloromethane; water;
DOI:10.1002/ejoc.201201119