β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

Base Information

• Chemical Name: β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)
• CAS No.: 1319720-88-1
• Molecular Formula: C₅₀H₄₁IrN₄O
• Molecular Weight: 906.122
• Mol file: 1319720-88-1.mol

Synonyms:β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

Chemical Property of β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

There total 2 articles about β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

Iodoethanol (624-76-0) + (5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1) → β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1319720-88-1)

Guidance literature:

With NaOH; NaBH₄; In tetrahydrofuran; sodium hydroxide; aq. NaOH; addn. of degassed aq. soln. of NaOH and NaBH4 to degassed THF soln. of iridium compd., heating at 70°C for 2 h, cooling to room temp., addn. of iodoethanol, stirring for 15 min at room temp.; evapn., washing with water, chromy. (alumina, CH2Cl2/hexanes (1:1)), NMR;

DOI:10.1139/v11-126

Reference yield: 92.0%

Iodoethanol (624-76-0) + chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III) (872415-81-1) → β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1319720-88-1)

Guidance literature:

chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III); With sodium tetrahydroborate; sodium hydroxide; In tetrahydrofuran; at 70 ℃; for 2h;

Iodoethanol; In tetrahydrofuran; at 20 ℃; for 15h;

DOI:10.1139/v11-126

Reference yield: 80.0%

pyridine (110-86-1) + phthalimide (136918-14-4,85-41-6) + β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1319720-88-1) → [Ir(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(pyridine)(CH2CH2NC8H4O2)] (1350519-13-9)

Guidance literature:

In pyridine; High Pressure; heating degassed mixt. of iridium compd., phthalimide and pyridine, heating to 150°C for 15 h; evapn., dissolving in CDCl3, addn. of hexane, washing with water, chromy. (alumina, CH2Cl2/hexanes (1:1)), evapn., NMR and MS;

DOI:10.1139/v11-126

upstream raw materials:

Iodoethanol

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)

Downstream raw materials:

Ir(ttp)C₆D₆

[Ir(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(THF)(phthalimide)]

[Ir(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(pyridine)(CH₂CH₂NC₈H₄O₂)]

Ir(ttp)(C₄H₈O)(NC₄H₈O₂)