Phenol,4-ethenyl-2-methoxy-, homopolymer

Base Information

• Chemical Name: Phenol,4-ethenyl-2-methoxy-, homopolymer
• CAS No.: 31853-85-7
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.177
• Mol file: 31853-85-7.mol

Synonyms:Phenol,2-methoxy-4-vinyl-, polymers (8CI);3-Methoxy-4-hydroxystyrene polymer;4-Hydroxy-3-methoxystyrene polymer;4-Vinyl-2-methoxyphenol homopolymer;Poly(3-methoxy-4-hydroxystyrene);Poly(4-hydroxy-3-methoxystyrene);Poly(4-vinylguaiacol);Poly(vinylguaiacol);4-ethenyl-2-methoxyphenol;2-Methoxy-4-ethenylphenol;3-Methoxy-4-hydroxystyrene;o-Methoxy-p-vinylphenol;Phenol, 2-methoxy-4-vinyl-;phenol, 4-ethenyl-2-methoxy-;

Chemical Property of Phenol,4-ethenyl-2-methoxy-, homopolymer

Chemical Property:

• Boiling Point: 245 °C at 760 mmHg
• Flash Point: 111.3 °C
• Density: 1.089 g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenol,4-ethenyl-2-methoxy-, homopolymer

There total 44 articles about Phenol,4-ethenyl-2-methoxy-, homopolymer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid (1135-24-6,537-98-4) → 3-methoxy-4-hydroxystyrene (7786-61-0,31853-85-7)

Guidance literature:

With phosphate buffer; Catharanthus roseus; at 25 ℃; for 72h; pH=6.0;

DOI:10.1248/cpb.49.639

Reference yield: 98.0%

3-(4-hydroxy-3-methoxyphenyl)acrylic acid (1135-24-6,537-98-4) → 3-methoxy-4-hydroxystyrene (7786-61-0,31853-85-7)

Guidance literature:

With ferulic acid decarboxylase from Enterobacter sp; In aq. phosphate buffer; at 30 ℃; for 19h; pH=7; Sealed tube; Enzymatic reaction;

DOI:10.1021/acs.orglett.8b02058

Reference yield: 95.0%

4-acetoxy-3-methoxyvinylbenzene (46316-15-8) → 3-methoxy-4-hydroxystyrene (7786-61-0,31853-85-7)

Guidance literature:

With cucumber juice; at 30 - 35 ℃; for 6h; Inert atmosphere; Green chemistry;

DOI:10.1039/c6ra01760f

upstream raw materials:

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid

4,4-(ethane-1,1-diyl)bis(2-methoxyphenol)

methyl magnesium iodide

diethyl ether

Downstream raw materials:

4-benzoyloxy-3-methoxy-styrene

4-hydroxy-3-methoxyphenyl-propanal

N,N-dimethyl-ethanamine

benzene-1,2-diol

Refernces

• 1、 Mishra, Shashank,Sachan, Ashish,Vidyarthi, Ambarish Sharan,Sachan, Shashwati Ghosh. "Microbial production of 4-vinylguaiacol from ferulic acid by Bacillus cereus SAS-3006". . p. 259 - 266. Retrieved 2014.
• 2、 Dong, Kui,Zhao, Chuang-Yuan,Wang, Xiao-Ju,Wu, Li-Zhu,Liu, Qiang. "Bioinspired Selective Synthesis of Heterodimer 8-5′ or 8- O-4′ Neolignan Analogs". . p. 2816 - 2820. Retrieved 2021.
• 3、 Hua, Dong-Liang,Liang, Xiao-Hui,Zhang, Xiao-Dong,Zhang, Jie,Xu, Hai-Peng,Li, Yan,Xu, Ping. "Rapid transformation of ferulic acid to 4-vinyl guaiacol by Bacillus pumilus S-1". . p. 615 - 617. Retrieved 2013.
• 4、 Darapureddi, Prabhakara Rao,Nayak, Rati Ranjan. "Synthesis, Surface Properties and Effect of an Amino Acid Head Group of 11-(2-Methoxy-4-vinylphenoxy)undecanoicacid-Based Anionic Surfactants". . p. 1133 - 1142. Retrieved 2016.
• 5、 Phillips,Goss. "-". . p. 1436,1439. Retrieved 1932.
• 6、 Cardona-G, Wilson,Hernández, Cristian,Herrera-R, Angie,Moreno, Gustavo. "New hybrids based on curcumin and resveratrol: Synthesis, cytotoxicity and antiproliferative activity against colorectal cancer cells". . . Retrieved 2021/05/26.
• 7、 Avenda?o Villarreal, Jesus Alberto,Delolo, Fábio Godoy,Granato, Artur Vicari,Gusevskaya, Elena Vitalievna,dos Santos, Eduardo Nicolau. "The first one-pot metathesis-hydroformylation procedure: a straight synthesis of 2-arylpropanals from renewable 1-propenylbenzenes". . p. 8007 - 8013. Retrieved 2021/12/27.