((CH₃)3CC₆H₂CH₂O)4(C₆H₅CH₂)2(CH₃C₅H₃NC₅H₃NCH₂)2

Base Information

• Chemical Name: ((CH₃)3CC₆H₂CH₂O)4(C₆H₅CH₂)2(CH₃C₅H₃NC₅H₃NCH₂)2
• CAS No.: 340814-74-6
• Molecular Formula: C₈₂H₈₈N₄O₄
• Molecular Weight: 1193.63
• Mol file: 340814-74-6.mol

Synonyms:((CH₃)3CC₆H₂CH₂O)4(C₆H₅CH₂)2(CH₃C₅H₃NC₅H₃NCH₂)2

Chemical Property of ((CH₃)3CC₆H₂CH₂O)4(C₆H₅CH₂)2(CH₃C₅H₃NC₅H₃NCH₂)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((CH₃)3CC₆H₂CH₂O)4(C₆H₅CH₂)2(CH₃C₅H₃NC₅H₃NCH₂)2

There total 1 articles about ((CH₃)3CC₆H₂CH₂O)4(C₆H₅CH₂)2(CH₃C₅H₃NC₅H₃NCH₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

benzyl chloride (100-44-7) + 5,11,17,23-tetra(tert-butyl)-26,28-bis<(6-methyl-2,2'-bipyridyl-6'-yl)methoxy>calix<4>arene-25,27-diol (162845-58-1) → ((CH3)3CC6H2CH2O)4(C6H5CH2)2(CH3C5H3NC5H3NCH2)2 (340814-74-6)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide;

DOI:10.1016/S0040-4039(01)00262-3

Reference yield: 98.0%

cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) + ((CH3)3CC6H2CH2O)4(C6H5CH2)2(CH3C5H3NC5H3NCH2)2 (340814-74-6) → CoCl2(CH3C5H3NC5H3NCH2)((CH3)3CC6H2CH2O)4(C6H5CH2)2CoCl2(CH3C5H3NC5H3NCH2) (437702-11-9)

Guidance literature:

In dichloromethane; acetonitrile; mixture of soln. of CoCl2 in CH3CN and soln. of calix(4)arene-based podand in CH2Cl2 stirred at room temp. for 1 h; concentration to dryness, treating with CH2Cl2, filtration, filtrate concentration; elem. anal.;

DOI:10.1002/1099-0682(200203)2002:4<901::AID-EJIC901>3.0.CO;2-9

Reference yield: 90.0%

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + dichloromethane (75-09-2) + ((CH3)3CC6H2CH2O)4(C6H5CH2)2(CH3C5H3NC5H3NCH2)2 (340814-74-6) → copper(I)((CH3)3CC6H2CH2O)4(C6H5CH2)2(CH3C5H3NC5H3NCH2)2 hexafluorophosphate*0.8CH2Cl2

Guidance literature:

In acetonitrile; starting materials stirred in CH3CN until suspension dissolved; evapn. of solvent to dryness, chromy. (Al2O3, CH2Cl2); elem. anal.;

DOI:10.1002/1099-0682(200203)2002:4<901::AID-EJIC901>3.0.CO;2-9

upstream raw materials:

benzyl chloride

5,11,17,23-tetra(tert-butyl)-26,28-bis<(6-methyl-2,2'-bipyridyl-6'-yl)methoxy>calix<4>arene-25,27-diol

Downstream raw materials:

CoCl₂(CH₃C₅H₃NC₅H₃NCH₂)((CH₃)3CC₆H₂CH₂O)4(C₆H₅CH₂)2CoCl₂(CH₃C₅H₃NC₅H₃NCH₂)