5-(2'-formylphenyl)-10,15,20-triphenylporphyrin

Base Information

Chemical Name:5-(2'-formylphenyl)-10,15,20-triphenylporphyrin
CAS No.:125187-60-2
Molecular Formula:C₄₅H₃₀N₄O
Molecular Weight:642.759
Hs Code.:

Synonyms:5-(2'-formylphenyl)-10,15,20-triphenylporphyrin

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Chemical Property of 5-(2'-formylphenyl)-10,15,20-triphenylporphyrin

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Technology Process of 5-(2'-formylphenyl)-10,15,20-triphenylporphyrin

There total 7 articles about 5-(2'-formylphenyl)-10,15,20-triphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 5-[2'-(1'',3''-dithiacyclohexan-2''-yl)phenyl]-10,15,20-triphenylporphyrin

: 125187-60-2
5-(2'-formylphenyl)-10,15,20-triphenylporphyrin

Guidance literature:: With boron trifluoride diethyl etherate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃;
DOI:10.1039/b109377k

Reference yield: 68.0%

: 67066-09-5
5-bromo-10,20-dihexyl-15-phenylporphyrin (5)

: 40138-16-7
2-formylbenzene boronic acid

: 125187-60-2
5-(2'-formylphenyl)-10,15,20-triphenylporphyrin

Guidance literature:: With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 80 ℃; for 15h; Inert atmosphere;
DOI:10.1002/chem.202002394

Reference yield:

: 100-52-7
benzaldehyde

: 125187-60-2
5-(2'-formylphenyl)-10,15,20-triphenylporphyrin

Guidance literature:: Multi-step reaction with 4 steps

1.1: trifluoroacetic acid / dichloromethane / 0.3 h / Inert atmosphere

1.2: 1 h / Inert atmosphere; Darkness

2.1: tetrahydrofuran; dibutyl ether / 0.67 h / 20 °C / Inert atmosphere

2.2: 0.25 h / Inert atmosphere

3.1: N-Bromosuccinimide / dichloromethane / 3 h / 0 - 25 °C

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium phosphate / tetrahydrofuran / 15 h / 80 °C / Inert atmosphere

With potassium phosphate; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; trifluoroacetic acid; In tetrahydrofuran; dichloromethane; dibutyl ether; 4.1: |Suzuki-Miyaura Coupling;
DOI:10.1002/chem.202002394