Synonyms:Methane,thiobis[trifluoro- (9CI); Sulfide, bis(trifluoromethyl) (6CI,8CI);Bis(trifluoromethyl) sulfide; Bis(trifluoromethyl) thioether; Perfluorodimethylsulfide; Perfluoromethyl sulfide; Trifluoromethyl sulfide
98%Min *data from raw suppliers
BIS(TRIFLUOROMETHYL)SULFIDE 95.00% *data from reagent suppliers
There total 54 articles about bis(trifluoromethyl)sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
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The study presents the synthesis and characterization of the first organosilver(III) fluoride complex, [PPh4][(CF3)3AgF], which is a significant contribution to the field of fluorination processes. The researchers used trifluoromethyl groups (CF3) to stabilize the silver(III) center, and the complex was prepared through a series of reactions involving the chlorination of the organosilver(I) complex [CF3AgCF3]? to form [PPh4][(CF3)3AgCl], which was then treated with AgF to obtain the desired fluoro-complex [PPh4][(CF3)3AgF]. The purpose of these chemicals was to create a compound that could provide insights into silver-mediated fluorination processes, and to explore the reactivity and stability of the Ag–F bond within this complex. The study found that while the Ag–F bond was strong and withstood harsh conditions, it was also reactive, undergoing solvolysis with thiols to form thiolato complexes that could be converted into trifluoromethyl thioethers under mild conditions.
The study presents a novel method for the nucleophilic trifluoromethylthiolation of aryl halides using a series of air-stable copper reagents. These reagents, which contain a trifluoromethylthio group (-SCF3), are significant in the synthesis of compounds found in pharmaceuticals and agrochemicals due to their high lipophilicity and hydrophobicity. The researchers synthesized copper(I) trifluoromethylthiolate complexes using simple copper salts, elemental sulfur, a trifluoromethyl source (CF3SiMe3), and electron-donating ligands such as bipyridine derivatives. The purpose of these chemicals was to develop a cost-effective and easily storable reagent for the direct conversion of aryl halides into trifluoromethylthioethers, which are valuable in various chemical industries. The study demonstrates the efficiency of these copper reagents in producing aryl trifluoromethyl thioethers with a wide range of aryl and heteroaryl halides, offering a new and convenient approach to trifluoromethylthiolation.
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