INDIUM DIISOPROPYLDITHIOCARBAMATE

Base Information

• Chemical Name: INDIUM DIISOPROPYLDITHIOCARBAMATE
• CAS No.: 87052-01-5
• Molecular Formula: C₂₁H₄₂InN₃S₆
• Molecular Weight: 643.801
• Mol file: 87052-01-5.mol

Synonyms:indium(III) tris(di-n-propyldithiocarbamate)

Chemical Property of INDIUM DIISOPROPYLDITHIOCARBAMATE

Chemical Property:

• Melting Point: >270°C

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of INDIUM DIISOPROPYLDITHIOCARBAMATE

There total 2 articles about INDIUM DIISOPROPYLDITHIOCARBAMATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.2%

indium (7440-74-6) + dipropylammonium dipropyldithiocarbamate (39234-20-3) → indium(III) tris(di-n-propyldithiocarbamate) (87052-01-5)

Guidance literature:

With sodium hydroxide; In hydrogenchloride; acetone; metallic indium was dissolved in HCl, pH was adjusted to 3-4 with aq. NaOH, (n-Pr)2NH2S2CN(n-Pr)2 with excess of CS2 in acetone was added; react. mixt. was concd., ppt. was filtered and recrystd. from chloroform/ethanol; elem. anal.;

DOI:10.1016/S0040-6031(99)00322-6

Reference yield:

indium(III) chloride (10025-82-8) + dipropylammonium dipropyldithiocarbamate (39234-20-3) → indium(III) tris(di-n-propyldithiocarbamate) (87052-01-5)

Guidance literature:

In water; InCl3 reacted with ligand (molar ratio 1:3) in water; accordingly to A. G. Souza et al., J. Thermal Anal., 49 (1997) 679 and M. M. Oliveira et al., Thermochim. Acta, 328 (1999) 223; filtered; recrystd. from acetone; dried in vac.; elem. anal.;

DOI:10.1023/A:1013971031425

Reference yield:

indium(III) tris(di-n-propyldithiocarbamate) (87052-01-5) → indium (7440-74-6)

Guidance literature:

In neat (no solvent); sample heating at 10 K/min in N2 flux 0.83 ml/s up to 385°C; TG/DTG;

DOI:10.1016/s0040-6031(98)00646-7

upstream raw materials:

indium

dipropylammonium dipropyldithiocarbamate

indium(III) chloride

Downstream raw materials:

indium

Refernces

• 1、 Souza,Oliveira,Santos,Conceicao,Nunes,Machado. "Kinetic analysis of the thermal decomposition of dialkyldithio-carbamates chelates of indium(III)". . p. 359 - 363. Retrieved 2008/10/08.