n-Hendecane

Base Information

• Chemical Name: n-Hendecane
• CAS No.: 1120-21-4
• Deprecated CAS: 1714962-75-0
• Molecular Formula: C11H24
• Molecular Weight: 156.312
• Hs Code.: 29011090
• European Community (EC) Number: 214-300-6
• NSC Number: 66159
• UN Number: 2330
• UNII: JV0QT00NUE
• DSSTox Substance ID: DTXSID9021689
• Nikkaji Number: J1.759K
• Wikipedia: Undecane
• Wikidata: Q150731
• RXCUI: 1811767
• Metabolomics Workbench ID: 5286
• ChEMBL ID: CHEMBL132474
• Mol file: 1120-21-4.mol

Synonyms:Halpaclean;Hendecane;Nikko Elace;n-Undecane;

Chemical Property of n-Hendecane

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: <0.4 mm Hg ( 20 °C)
• Melting Point: -26 °C(lit.)
• Refractive Index: n20/D 1.417(lit.)
• Boiling Point: 196.3 °C at 760 mmHg
• Flash Point: 60 °C
• PSA: 0.00000
• Density: 0.743 g/cm³
• LogP: 4.53710
• Storage Temp.: Store below +30°C.
• Water Solubility.: IMMISCIBLE
• XLogP3: 5.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 156.187800766
• Heavy Atom Count: 11
• Complexity: 49.1
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

Undecane [Standard Material for GC] >99.5%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 36/37/38-65-66
• Safety Statements: 26-36-24/25-62

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Solvents -> Aliphatics, Saturated (
• Canonical SMILES: CCCCCCCCCCC
• Uses: Petroleum research, organic synthesis, distillation chaser. Undecane is used in preparation method of small-size hollow Silicon Dioxide. Undecane is mainly used as a model n-alkane in studies relating to viscosities, excess molar enthalpies and vapor-liquid equilibrium of binary alkane mixtures.

Technology Process of n-Hendecane

There total 257 articles about n-Hendecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

lauric acid (143-07-7) → n-Undecane (1120-21-4) + laurone (540-09-0)

Guidance literature:

With iron; In neat (no solvent); at 298 ℃; for 5h;

Reference yield:

dodecanoyl 4-pentenoyl peroxide (103227-40-3) → n-Undecane (1120-21-4) + 1-pentadecene (13360-61-7)

Guidance literature:

at -78 ℃; for 50h; Irradiation;

DOI:10.1016/S0040-4020(01)97195-9

Reference yield:

4-carbonyloxybutyryl dodecanoyl peroxide (103227-50-5) → n-Undecane (1120-21-4) + palmitic acid (1002-84-2)

Guidance literature:

at -78 ℃; for 50h; Irradiation;

DOI:10.1016/S0040-4020(01)97195-9

upstream raw materials:

cuscohygrine

methanol

potassium laurate

n-dodecanoyl chloride

Downstream raw materials:

1-chloroundecane

(E)-2-undecene

1-undecene

(Z)-2-undecene

Refernces

• 1、 Graenacher. "-". . p. 737. Retrieved 1920.
• 2、 Chatgilialoglu, Chryssostomos,Lucarini, Marco. "Rate Constants for the Reaction of Acyl Radicals with Bu3SnH and (TMS)3SiH". . p. 1299 - 1302. Retrieved 1995.
• 3、 Rahi, Reena,Fang, Minfeng,Ahmed, Atif,Sánchez-Delgado, Roberto A.. "Hydrogenation of quinolines, alkenes, and biodiesel by palladium nanoparticles supported on magnesium oxide". . p. 14490 - 14497. Retrieved 2012.
• 4、 Rieke, Ross D.,Thakur, Deepak S.,Roberts, Brian D.,White, Geoffrey T.. "Fatty methyl ester hydrogenation to fatty alcohol part I: Correlation between catalyst properties and activity/selectivity". . p. 333 - 339. Retrieved 1997.
• 5、 Terao, Jun,Naitoh, Yoshitaka,Kuniyasu, Hitoshi,Kambe, Nobuaki. "Cross-coupling of alkyl halides with Grignard reagents using nickel and palladium complexes bearing η3-allyl ligand as catalysts". . p. 825 - 827. Retrieved 2007.
• 6、 Qin, Shengxiang,Li, Teng,Zhang, Man,Liu, Hongyu,Yang, Xin,Rong, Nianxin,Jiang, Jun,Wang, Yalin,Zhang, Hua,Yang, Weiran. "Catalyst-free synthesis of biodiesel precursors from biomass-based furfuryl alcohols in the presence of H2O and air". . p. 6326 - 6334. Retrieved 2019.
• 7、 Leger, Bastien,Menuel, Stephane,Ponchel, Anne,Hapiot, Frederic,Monflier, Eric. "Nanoparticle-based catalysis using supramolecular hydrogels". . p. 1269 - 1272. Retrieved 2012.
• 8、 Anderson et al.. "-". . p. 869. Retrieved 1969.
• 9、 Anderson, Thomas J.,Jones, Gavin D.,Vicic, David A.. "Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles". . p. 8100 - 8101. Retrieved 2004.
• 10、 Liu, Dajiang,Chen, Eugene Y.-X.. "Diesel and alkane fuels from biomass by organocatalysis and metal-acid tandem catalysis". . p. 2236 - 2239. Retrieved 2013.