3,3-dimethyl-1-(trifluoromethylsulfonyl)-1,3-azasilolidine

Base Information

• Chemical Name: 3,3-dimethyl-1-(trifluoromethylsulfonyl)-1,3-azasilolidine
• CAS No.: 1338487-88-9
• Molecular Formula: C₆H₁₂F₃NO₂SSi
• Molecular Weight: 247.313
• Mol file: 1338487-88-9.mol

Synonyms:3,3-dimethyl-1-(trifluoromethylsulfonyl)-1,3-azasilolidine

Chemical Property of 3,3-dimethyl-1-(trifluoromethylsulfonyl)-1,3-azasilolidine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 3,3-dimethyl-1-(trifluoromethylsulfonyl)-1,3-azasilolidine

There total 2 articles about 3,3-dimethyl-1-(trifluoromethylsulfonyl)-1,3-azasilolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

Trifluoromethanesulfonamide (421-85-2) + 2-bromoethyl(chloromethyl)dimethylsilane (1338487-87-8) → 2,2,6,6-tetramethyl-4-(trifluoromethylsulfonyl)-1,4,2,6-oxaazadisilinane (1262320-78-4) + 3,3-dimethyl-1-(trifluoromethylsulfonyl)-1,3-azasilolidine (1338487-88-9) + 1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane (2362-10-9)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 - 65 ℃; Inert atmosphere;

DOI:10.1134/S1070363211080287

Reference yield: 13.0%

methanol (67-56-1) + Trifluoromethanesulfonamide (421-85-2) + 2-bromoethyl(chloromethyl)dimethylsilane (1338487-87-8) → (chloromethyl)methoxydimethylsilane (18143-33-4) + 2,2,6,6-tetramethyl-4-(trifluoromethylsulfonyl)-1,4,2,6-oxaazadisilinane (1262320-78-4) + 3,3-dimethyl-1-(trifluoromethylsulfonyl)-1,3-azasilolidine (1338487-88-9) + 1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane (2362-10-9)

Guidance literature:

With triethylamine; at 20 ℃; Reflux;

DOI:10.1134/S1070363211080287

upstream raw materials:

methanol

Trifluoromethanesulfonamide

2-bromoethyl(chloromethyl)dimethylsilane